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Author: Subject: Barium peroxide from barium carbonate
Chemgineer
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[*] posted on 19-7-2023 at 10:38


Quote: Originally posted by Sir_Gawain  
Sodium and magnesium sulfate are quite soluble in water. I fail to see how that is a problem.


I didn't mean it was a huge problem, just when you've got a huge solid lump of the mixture in there after a dry distillation it can be tedious to remove it.
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[*] posted on 19-7-2023 at 15:19


Been there, I setup a boiling pot, add baking soda and let it simmer for a few hours. It might be soluble, but a large rock is slow to disolive



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[*] posted on 19-7-2023 at 20:42


I still don't understand what was wrong with just using acetate. Why faff around trying to make a nitrate? It's more expensive, more dangerous (even if only slightly) and more damaging to dispose of. Acetic acid is cheap, everywhere, and should work fine.

BaCO3 (s) + 2 AcOH >> Ba(OAc)2 (aq) + CO2 (g)

Ba(OAc)2 (s) + H2O2 (NaOAc buffer) >> BaO2 (s) + 2 AcOH




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[*] posted on 20-7-2023 at 01:21


I haven't found any references for the acetate reaction.



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