Sciencemadness Discussion Board

Phosporus Cation

Vargouille - 27-6-2012 at 15:07

Looking at articles, I found that some German scientists made a cation of phosphorus, P9+, and althought unable to read the article, the image given makes me think it involved a nitrosation of white phosphorus and subsequent reaction with another molecule of white phosphorus. Can anyone with access elaborate here on the process or provide a link to a free copy of the article?

Link to original article I couldn't access:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201203991/ab...

snday - 27-6-2012 at 23:04

I also.

AndersHoveland - 28-6-2012 at 01:58

This type of thing is not extremely unusual. I have not read the article but I would be surprised if super lewis acids (fluoride ion abductors) were not involved.