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Author: Subject: Phosporus Cation
Vargouille
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[*] posted on 27-6-2012 at 15:07
Phosporus Cation


Looking at articles, I found that some German scientists made a cation of phosphorus, P9+, and althought unable to read the article, the image given makes me think it involved a nitrosation of white phosphorus and subsequent reaction with another molecule of white phosphorus. Can anyone with access elaborate here on the process or provide a link to a free copy of the article?

Link to original article I couldn't access:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201203991/ab...
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snday
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[*] posted on 27-6-2012 at 23:04


I also.



AndersHoveland
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[*] posted on 28-6-2012 at 01:58


This type of thing is not extremely unusual. I have not read the article but I would be surprised if super lewis acids (fluoride ion abductors) were not involved.
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