Sciencemadness Discussion Board

Looking for new experimental evidence for some EAS mechanisms

sqrtpapi2001 - 2-11-2021 at 10:42

In The Art of ... Mechanisms by Robert Grossman, he claims the standard-taught mechanisms for the intermediates involved in EAS nitration and F-C acetylation have been recently experimentally invalidated. He proposes the (see attached) alternative mechanism for the nitration, for example.

Could someone point me in the right direction of verifying such claims in the literature? Any papers, articles, etc. Thanks.

Grossman pg 155 (1).PNG - 158kB

[Edited on 2-11-2021 by sqrtpapi2001]