Difference between revisions of "Octyl acetate"
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| − | [[ | + | {{Chembox |
| + | | Name = Octyl acetate | ||
| + | | Reference = | ||
| + | | IUPACName = Octyl acetate | ||
| + | | PIN = | ||
| + | | SystematicName = | ||
| + | | OtherNames = Caprylyl acetate<br>Octyl ethanoate<br>n-Octyl acetate | ||
| + | <!-- Images --> | ||
| + | | ImageFile = Octyl_acetate_structure.png | ||
| + | | ImageSize = 300 | ||
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| + | <!-- Sections --> | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | 3DMet = | ||
| + | | Abbreviations = | ||
| + | | SMILES = | ||
| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | AtmosphericOHRateConstant = | ||
| + | | Appearance = Colorless liquid | ||
| + | | BoilingPt = | ||
| + | | BoilingPtC = 211 | ||
| + | | BoilingPt_ref = | ||
| + | | BoilingPt_notes = | ||
| + | | Density = 0.863–0.87 g/cm<sup>3</sup> | ||
| + | | Formula = C<sub>10</sub>H<sub>20</sub>O<sub>2</sub> | ||
| + | | HenryConstant = | ||
| + | | LogP = | ||
| + | | MolarMass = 172.27 g/mol | ||
| + | | MeltingPt = | ||
| + | | MeltingPtC = -38.5 | ||
| + | | MeltingPt_ref = | ||
| + | | MeltingPt_notes = | ||
| + | | Odor = Fruity, slightly waxy floral odor | ||
| + | | pKa = | ||
| + | | pKb = | ||
| + | | Solubility = 0.021 g/100 g (0 °C)<br>0.018 g/100 g (29.7 °C)<br>0.018 g/100 g (40 °C)<br>0.012 g/100 g (92.1 °C) | ||
| + | | SolubleOther = Miscible with [[diethyl ether]], [[ethanol]], [[ethyl acetate]] | ||
| + | | Solvent = | ||
| + | | VaporPressure = 0.01 kPa (−3 °C)<br>0.0072–0.0073 (14.75 °C)<br>0.02–0.1 kPa (27 °C)<br>1 kPa (66.3 °C)<br>10 kPa (120 °C) | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Coordination = | ||
| + | | CrystalStruct = | ||
| + | | MolShape = | ||
| + | }} | ||
| + | | Section4 = {{Chembox Thermochemistry | ||
| + | | DeltaGf = | ||
| + | | DeltaHc = | ||
| + | | DeltaHf = | ||
| + | | Entropy = | ||
| + | | HeatCapacity = 331–343.74 J·mol<sup>-1</sup>·K<sup>-1</sup> | ||
| + | }} | ||
| + | | Section5 = {{Chembox Explosive | ||
| + | | ShockSens = | ||
| + | | FrictionSens = | ||
| + | | DetonationV = | ||
| + | | REFactor = | ||
| + | }} | ||
| + | | Section6 = {{Chembox Hazards | ||
| + | | AutoignitionPt = | ||
| + | | ExploLimits = | ||
| + | | ExternalMSDS = [https://www.docdroid.net/rmGbNZj/octyl-acetate-sa.pdf.html Sigma-Aldrich] | ||
| + | | FlashPt = 86 °C (187 °F; 359 K) | ||
| + | | LD50 = 3,000 mg/kg (rat, oral) | ||
| + | | LC50 = | ||
| + | | MainHazards = Irritant | ||
| + | | NFPA-F = | ||
| + | | NFPA-H = | ||
| + | | NFPA-R = | ||
| + | | NFPA-S = | ||
| + | }} | ||
| + | | Section7 = {{Chembox Related | ||
| + | | OtherAnions = | ||
| + | | OtherCations = | ||
| + | | OtherFunction = | ||
| + | | OtherFunction_label = | ||
| + | | OtherCompounds = [[Ethyl acetate]] | ||
| + | }} | ||
| + | }} | ||
'''Octyl acetate''' is an [[ester]] which is commonly found in citrus fruits. | '''Octyl acetate''' is an [[ester]] which is commonly found in citrus fruits. | ||
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===Physical=== | ===Physical=== | ||
| − | Octyl acetate is insoluble in water but soluble in ethanol, [[1-octanol]] and [[diethyl ether]]. It has a fruity smell. Octyl acetate has a wide liquid range. It melts at - | + | Octyl acetate is insoluble in water but soluble in ethanol, [[1-octanol]] and [[diethyl ether]]. It has a fruity smell. Octyl acetate has a wide liquid range. It melts at -38 °C and boils at 211 °C. |
==Availability== | ==Availability== | ||
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==Projects== | ==Projects== | ||
*Extract octyl acetate from oranges or grapefruits | *Extract octyl acetate from oranges or grapefruits | ||
| + | *Fragrant compound collecting | ||
==Handling== | ==Handling== | ||
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===Storage=== | ===Storage=== | ||
| − | Should be stored in closed bottles, away from any flame source. | + | Should be stored in glass closed bottles, away from any flame source. |
===Disposal=== | ===Disposal=== | ||
| − | Octyl acetate | + | Octyl acetate should be mixed with a more flammable solvent and safely burned. |
==References== | ==References== | ||
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[[Category:Organic compounds]] | [[Category:Organic compounds]] | ||
[[Category:Esters]] | [[Category:Esters]] | ||
| − | |||
[[Category:Fragrant compounds]] | [[Category:Fragrant compounds]] | ||
[[Category:Materials unstable in basic solution]] | [[Category:Materials unstable in basic solution]] | ||
| + | [[Category:Liquids]] | ||
Latest revision as of 20:57, 2 February 2020
| |
| Names | |
|---|---|
| IUPAC name
Octyl acetate
| |
| Other names
Caprylyl acetate
Octyl ethanoate n-Octyl acetate | |
| Properties | |
| C10H20O2 | |
| Molar mass | 172.27 g/mol |
| Appearance | Colorless liquid |
| Odor | Fruity, slightly waxy floral odor |
| Density | 0.863–0.87 g/cm3 |
| Melting point | −38.5 °C (−37.3 °F; 234.7 K) |
| Boiling point | 211 °C (412 °F; 484 K) |
| 0.021 g/100 g (0 °C) 0.018 g/100 g (29.7 °C) 0.018 g/100 g (40 °C) 0.012 g/100 g (92.1 °C) | |
| Solubility | Miscible with diethyl ether, ethanol, ethyl acetate |
| Vapor pressure | 0.01 kPa (−3 °C) 0.0072–0.0073 (14.75 °C) 0.02–0.1 kPa (27 °C) 1 kPa (66.3 °C) 10 kPa (120 °C) |
| Thermochemistry | |
| Hazards | |
| Safety data sheet | Sigma-Aldrich |
| Flash point | 86 °C (187 °F; 359 K) |
| Lethal dose or concentration (LD, LC): | |
| LD50 (Median dose)
|
3,000 mg/kg (rat, oral) |
| Related compounds | |
| Related compounds
|
Ethyl acetate |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Octyl acetate is an ester which is commonly found in citrus fruits.
Contents
Properties
Chemical
Octyl acetate can hydrolyze to 1-octanol and acetic acid. It can also act as a solvent.
Physical
Octyl acetate is insoluble in water but soluble in ethanol, 1-octanol and diethyl ether. It has a fruity smell. Octyl acetate has a wide liquid range. It melts at -38 °C and boils at 211 °C.
Availability
Octyl acetate may be extracted from oranges or grapefruits.
Preparation
As octyl acetate is an ester of 1-octanol and acetic acid, it can be synthesized by adding the two together in dehydrating conditions, though this is difficult.
Projects
- Extract octyl acetate from oranges or grapefruits
- Fragrant compound collecting
Handling
Safety
Octyl acetate is not particularly toxic, but do not ingest lab-grade material.
Storage
Should be stored in glass closed bottles, away from any flame source.
Disposal
Octyl acetate should be mixed with a more flammable solvent and safely burned.
