Barium permanganate
Names | |
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IUPAC name
Barium permanganate
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Other names
Barium manganate(VII)
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Properties | |
Ba(MnO4)2 | |
Molar mass | 375.198 g/mol |
Appearance | Dark violet-brown crystals |
Odor | Odorless |
Density | 3.77 g/cm3 (20 °C) |
Melting point | 200 °C (392 °F; 473 K) Decomposes |
Boiling point | Decomposes |
62.5 g/100 ml (20 °C) | |
Solubility | Reacts with alcohols |
Vapor pressure | ~0 mmHg |
Hazards | |
Safety data sheet | HiMedia |
Flash point | Non-flammable |
Related compounds | |
Related compounds
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Barium manganate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It is often used to prepare more exotic permangante salts, by double displacement reaction with their sulfate salt.
Contents
[hide]Properties
Chemical
Addition of sulfuric acid to barium permangante will produce permanganic acid and even manganese heptoxide if the acid is concentrated enough.
Physical
Barium permangante is a dark purple or purple-brown solid, soluble in water.
Availability
Barium permanganate is sold by various lab suppliers.
Preparation
Barium permanganate may be produced by disproportionation of barium manganate in a mildly acidic solution.
Preparations relying on aqueous reactions of barium manganate are extremely slow process due to the low solubility of the manganate.
Projects
- Make permanganic acid
- Make ammonium permanganate
- Make exotic and unusual permanganates
Handling
Safety
Barium permanganate is corrosive and a strong oxidizer. Avoid contact with combustible materials and acids.
Storage
Barium permanganate should be kept in PE or glass containers, with a good lid.
Disposal
Addition of hydrogen peroxide will cause it to break down to manganese dioxide and barium oxide/hydroxide. Addition of sulfuric acid or a source of sulfate will precipitate barium sulfate, which is non-toxic, and can be dumped in trash.