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Author: Subject: Toluene > benzyl chloride
chucknorris
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[*] posted on 25-1-2013 at 22:10
Toluene > benzyl chloride


I found one method which uses toluene and hypochlorite, but I found no user references whatsoever.

Should the chlorination of toluene with HCl work as with benzyl alcohol? Toluene is otc, but benzyl alcohol is very difficult to obtain.
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Mercedesbenzene
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[*] posted on 25-1-2013 at 23:19


Chlorination of toluene uses Cl2, not HCl, with a black light it proceeds quite rapidly.
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Inny_G
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[*] posted on 26-1-2013 at 06:58


Mervedesbenzene i think your method would make chloro-toluenes rather than benzyl chloride.

Chucknorris, i cant really say anything specific about this because i'm just on my phone atm but it is possible to make phenol from toluene and there are detailed syntheses on youtube
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killer_lapin
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[*] posted on 26-1-2013 at 07:26


mercedesbenzene is right the substitution is mostly on the substituent it self, producing benzyl chloride. Here is a couple of synthesis ways http://www.erowid.org/archive/rhodium/chemistry/benzylchlori...
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Inny_G
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[*] posted on 26-1-2013 at 07:39


Ergh my bad. I was thinking of chlorobenzene rather than benzyl chloride
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cal
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[*] posted on 26-1-2013 at 08:16
Benzyl Alcohol


Benzyl Alcohol on eBay
http://www.ebay.com/itm/Benzyl-Alcohol-99-5-Pure-8-oz-Solven...




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blankets
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[*] posted on 26-1-2013 at 15:25


Benzyl alcohol http://lemelange.com/benzyl-alcohol.aspx
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Nicodem
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