Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: Chlorination
njl
National Hazard
****




Posts: 609
Registered: 26-11-2019
Location: under the sycamore tree
Member Is Offline

Mood: ambivalent

[*] posted on 8-1-2021 at 15:29
Chlorination


In Shulgin's report on the chlorination of 2C-H to 2C-C, he uses liquid chlorine as a reagent. Why can't chlorine gas just be bubbled through a solution of 2C-C in a suitable solvent?
View user's profile View All Posts By User
mackolol
Hazard to Others
***




Posts: 459
Registered: 26-10-2017
Member Is Offline

Mood: Funky

[*] posted on 10-1-2021 at 10:40


And who said it can't?
View user's profile View All Posts By User
Antigua
Hazard to Others
***




Posts: 155
Registered: 27-9-2020
Member Is Offline


[*] posted on 10-1-2021 at 10:47


Bubbling a stoichiometric amount of gas in is very difficult. Maybe with a help of air pump it would be easier, but he had access to dry ice and acetone, so why would he need to bother with some gas generators? It probably will work as long as suitable reaction conditions are employed.
View user's profile View All Posts By User
mackolol
Hazard to Others
***




Posts: 459
Registered: 26-10-2017
Member Is Offline

Mood: Funky

[*] posted on 10-1-2021 at 11:29


I don't really think, that slight excess would do bad in this case. At least with 2C-B overbromination doesn't readily ocurr.


[Edited on 10-1-2021 by mackolol]
View user's profile View All Posts By User

  Go To Top