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Paddywhacker
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I'll scan some of the more interesting experiments.
Maybe in the Christmas holidays I'll have time to scan the whole book, but not now.
Do you have a reference for the teacher's manual? There is at lease one one reagent that is detailed only there.
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Paddywhacker
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Benzoin -> Benzil oxidation with Cu[II]/NH4NO3
Oxidation of alpha-hydroxy ketones with aqueous copper and ammonium nitrate, from Mayo, Pike & Butcher.
  
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Paddywhacker
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An ethylbenzene -> an acetophenone with persulphate & Ag
Oxidize 4-ethylanisole to 4-methoxyacetophenone with aqueous ammonium persulphate and catalytic silver nitrate.
Followed by formation and characterization of the 2,4-dinitrophenylhydrazone.
From Mayo, Pike & Butcher.
  
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Paddywhacker
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A benzyl alcohol --> a benzaldehyde
Oxidizing piperonyl alcohol to piperonal using chromium trioxide immobilized on Amberlyst A-26 resin. This reagent is easy to prepare and is a mild
oxidizing agent with an easy workup.
 
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Paddywhacker
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Aryl aldehyde --> aryl nitrile
This transformation is carried out by means of an O-(dinitrophenyl)oxime. It requires O-(2,4-dinitrophenyl) hydroxylamine, the preparation of which I
do not have, but it is in the Mayo, Pike & Butcher's Instruction Manual If somebody would be kind enough to post it then the details will be
complete.
This is the last experiment from the book that I think really interesting. The rest are just the usual organic lab stuff.
  
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Paddywhacker
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O-(2,4-dinitrophenyl)hydroxylamine
In reference to the previous post, here is a reference to the production and use of O-hydroxylamines.
Attachment: JOC 2003 p7119 Legault & Charette, O-hydroxylamines.pdf (91kB)
This file has been downloaded 4960 times
[Edited on 27-9-2009 by Paddywhacker]
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franklyn
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Introduction to Laboratory Techniques - A very nice book , get this one !
http://www.blunted.us/df/books/Introduction%20To%20Laborator...
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franklyn
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Standards & Tests for Reagent Chemicals 1920
http://books.google.com/books/download/Standards_and_tests_f...
Standard Methods of Chemical Analysis vol 1 1920
http://books.google.com/books/download/Standard_methods_of_c...
Standard Methods of Chemical Analysis vol 2 1922
http://books.google.com/books/download/Standard_methods_of_c...
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JohnWW
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There are many other
chemistry ebooks of interest on the same page, http://www.blunted.us/df/books/ .
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franklyn
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Merck LAB TOOLS - A collection of 939 handy references and guides
http://www.tcnj.edu/~hunt/Lab%20Tools%20-%20Merck.pdf
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franklyn
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Analytical Chemistry : Qualitative Analysis , 1921
http://books.google.com/books/download/Analytical_chemistry....
Salt Analysis
www.angelfire.com/rock3/karuda/project.html
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franklyn
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The Hydrogen Bond
http://ia331312.us.archive.org/1/items/hydrogenbond031051mbp...
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franklyn
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Industrial Nitrogen Compounds & Explosives
6.5 MB edition from Google with higher resolution than the 2 MB SciMad library edition
http://books.google.com/books/download/Industrial_nitrogen_c...
Chlorine & chlorine products: including the manufacture of bleaching powder
Another from the same series
http://books.google.com/books/download/Chlorine___chlorine_p...
A Treatise on General and Industrial Inorganic Chemistry 1920
Ettore Molinari , Thomas Henry Pope , 876 pages ( 66 MB pdf )
http://books.google.com/books/download/Treatise_on_general_a...
This book is an invaluable resource. Referencing patents , it describes in detail
old production methods at a time of transition when these were being replaced
by modern processes. It's descriptions are detailed as those of Urbanski , such
as the section on Nitric acid , but does not explicitly discuss anything explosive
related. Information provided on common elements rivals abridged outlines of
Mellor , and beyond anything found in wikipedia.
This book holds many treasures. Methods of making Chlorates , a method for
producing NH4NO3 from Ca(NO3)2 is a marvel of simplicity. Other revelations
leave one baffled. " Ammonium Nitrite: NH4NO2. This compound is made by
the action of an electric discharge on moist air." Huh ? Well at least that
provides fresh insights and research leads.
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JohnWW
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All three of those ebooks on Google came back as "404 not found on this server"!
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JohnWW
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Re Franklyn's 3 books, above, on books.google.com: The links provided STILL give "404 not found on this server". If anyone has them, please upload
them to a file-hoster like Ifile or Rapidshare, and post the links here.
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watson.fawkes
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The first one's on archive.org: http://www.archive.org/details/IndustrialNitrogenCompoundsAndExplosives. There's a DJVU version at the bottom of the left sidebar.
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entropy51
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Quote: Originally posted by JohnWW  | | Re Franklyn's 3 books, above, on books.google.com: The links provided STILL give "404 not found on this server". If anyone has them, please upload
them to a file-hoster like Ifile or Rapidshare, and post the links here. |
| Quote: Originally posted by JohnWW | Wake up and smell the coffee, Entropy51! Any such "export restriction" on any software item is impossible to police! Software can be strong-encrypted
to hide its identity and content, and electronically transferred anonymously across national borders with impunity! For example, the U$ Govt. tried to
stop the encryption program PGP from being exported out of the U$A because it was too hard for the N$A to decrypt, but simply failed. And what about
the First Amendment?
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It seems like Google Books does a good job of policing the border with New Zealand. How does the coffee
smell this morning John? How's that impunity thing working out for you anyways?
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JohnWW
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I think I will (a) try using a high-anonymity/elite proxy-server located in the U$A to download those 3 files from Google Books, or failing that, (b)
search on Google for alternative downloading sources of them.
Unfortunately, the DJVU version of Industrial Nitrogen Compounds, at http://www.archive.org/stream/IndustrialNitrogenCompoundsAnd... , supposedly 9.38 Mb, can be neither downloaded nor (because of no compatible
browser plugin being available) viewed online.
P.S. After some difficulty, I was able to download the three PDF files using only a "transparent" U$ proxy-server, 66.63.165.7:3128 . Codeen
high-anonymity proxies cannot be used for files of this size; they download only the first 2.9 Mb of each file.
[Edited on 10-3-10 by JohnWW]
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franklyn
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Chemistry of the Carbon Compounds Vol I , von Richter , 1916
http://books.google.com/books/download/Organic_chemistry.pdf...
fuming_nitric_acid posted the "archive " edition of this back in 2008
http://www.archive.org/details/organicchemistry00richrich/or...
Chemistry of the Carbon Compounds Vol II , von Richter , 1922
http://books.google.com/books/download/Organic_chemistry.pdf...
Highly Hazardous Chemicals
http://www.ehs.psu.edu/hazmat/highly_hazardous_chemicals.pdf
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In the event of unforseen internet hazards consult this post _
http://www.sciencemadness.org/talk/viewthread.php?tid=9230#p...
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JohnWW
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Thanks, Franklyn. I was able to use the same transparent U$ proxy-server as before, 66.63.165.7:3128 , to download the Google Books item by Von
Richter.
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franklyn
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The Structure Of Crystals 1935
* djvu , 9 MB
http://ia331342.us.archive.org/0/items/structureofcryst03091...
* .pdf , 11 MB
http://ia331342.us.archive.org/0/items/structureofcryst03091...
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franklyn
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Organic Eectrode Processes 1958
Fully referenced overview of electrochemical organic synthesis.
An excerpt below on how to obtain CHCl3 from CaCl2 with acetone
in water using a copper anode.
DJVU - 6 MB
http://ia331313.us.archive.org/3/items/organicelectrode03106...
PDF - 8 MB
http://ia331313.us.archive.org/3/items/organicelectrode03106...
Other Formats
http://ia331313.us.archive.org/3/items/organicelectrode03106...
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franklyn
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http://www.sciencemadness.org/talk/viewthread.php?tid=13557#...
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franklyn
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A Course in Qualitative Chemical Analysis - 1916
Rather Basic Inorganic chemistry but far more detailed than anything you
would find in a textbook. Describes tests for determining the presence of
specific elements and compounds along with extensive solubility data on
salts of every description. The solubility tables at the end of the book are
worth while having a copy for refererence.
http://books.google.com/books/download/A_course_in_qualitati...
Separation and Identification of a Mixture of Cations
A worked out lab excercise that shows step by step how to determine
unknown element composition _
www.uncp.edu/home/mcclurem/courses/chm226/qualitative_analys...
While on the subject here is a site dedicated to just this sort of analysis
www.angelfire.com/rock3/karuda/project.html
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franklyn
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Small Moleule Crystallization
http://acaschool.iit.edu/lectures04/JLiangXtal.pdf
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