Sciencemadness Discussion Board
Not logged in [Login ]
Go To Bottom

Printable Version  
Author: Subject: diphenyl oxalate - an attempt....
kmno4
International Hazard
*****




Posts: 1495
Registered: 1-6-2005
Location: Silly, stupid country
Member Is Offline

Mood: No Mood

[*] posted on 21-2-2014 at 04:29
diphenyl oxalate - an attempt....


Post temporarily removed.

All thanks or complains please send to our local clown Bfesser.


[Edited on 21-2-2014 by kmno4]




Слава Україні !
Героям слава !
View user's profile View All Posts By User
Marvin
National Hazard
****




Posts: 995
Registered: 13-10-2002
Member Is Offline

Mood: No Mood

[*] posted on 21-2-2014 at 05:37


Much respect for trying this but please don't taste an experimental compound ever again.

Fingers crossed it is the ester.
View user's profile View All Posts By User
Mailinmypocket
International Hazard
*****




Posts: 1351
Registered: 12-5-2011
Member Is Offline

Mood: No Mood

[*] posted on 21-2-2014 at 06:03


This is very interesting! I remember reading some papers in which dimethyl oxalate is used with a Ti catalyst and phenol to produce the target compound. Might be another route to experiment with since dimethyl oxalate is so easy to prepare?

http://www.orgsyn.org/demo.aspx?prep=cv2p0414

http://www.paper.edu.cn/selfs/downpaper/wangshengping286217-...
View user's profile View All Posts By User
Marvin
National Hazard
****




Posts: 995
Registered: 13-10-2002
Member Is Offline

Mood: No Mood

[*] posted on 21-2-2014 at 06:50


Second paper isn't working for me, it goes directly to the site front page. Can you attach it?

That was the method I was going to try, but I didn't know about the catalyst. I was also thinking about transesterification.

View user's profile View All Posts By User
Mailinmypocket
International Hazard
*****




Posts: 1351
Registered: 12-5-2011
Member Is Offline

Mood: No Mood

[*] posted on 21-2-2014 at 07:31


Sure thing, no clue why that happened...



Attachment: DPO via Transesterification.pdf (109kB)
This file has been downloaded 1094 times
View user's profile View All Posts By User
bfesser
Resident Wikipedian
Thread Moved
21-2-2014 at 09:57

  Go To Top