ChocolateStirBar
Harmless
Posts: 13
Registered: 30-10-2017
Member Is Offline
Mood: No Mood
|
|
What on earth is my "Pyridine"?!
I bought what I assumed was pyridine a while ago alongside some other common solvents. It wasn't long until my lab started to smell very sweet and
ethereal, which I put down to being either the diethyl ether or the THF.
The THF was an amber glass bottle packaged next to the "pyridine" which was in a HDPE bottle, so I assumed the odour was coming from the THF. Having
transferred said "pyridine" to a reagent bottle, it is absolutely the source of the sweet smell. Now...absolutely everything I read is telling me that
this is NOT pyridine, as no smell of burnt coffee, nor fishy stench is detectable. Simply an ethereal sweetish smell which seems very very volatile,
as the reagent bottle is already giving off a slight whiff of it.
How do I test what the hell this stuff actually is? Are there any chances it was mixed up with something similar?
|
|
|
ninhydric1
Hazard to Others
Posts: 345
Registered: 21-4-2017
Location: Western US
Member Is Offline
Mood: Bleached
|
|
Try boiling point and freezing point first. These are usually good for indicating organic compounds in general. Due to the sweet smell, I assume it's
an ester, not pyridine.
The philosophy of one century is the common sense of the next.
|
|
|
DraconicAcid
International Hazard
Posts: 4333
Registered: 1-2-2013
Location: The tiniest college campus ever....
Member Is Offline
Mood: Semi-victorious.
|
|
Also check to see if it's water-soluble, and measure its density. If it is even slightly water soluble, check the pH of the solution.
And yeah- if it smells sweet, or even tolerable, it ain't pyridine.
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
|
|
|
ChocolateStirBar
Harmless
Posts: 13
Registered: 30-10-2017
Member Is Offline
Mood: No Mood
|
|
It is water soluble and the smell became much more apparent even under strong ventilation upon addition of water, but no "white mist" was observed as
has been reported with actual pyridine + water.
I'll check the pH tomorrow and report back.
|
|
|
nezza
Hazard to Others
Posts: 324
Registered: 17-4-2011
Location: UK
Member Is Offline
Mood: phosphorescent
|
|
If it smells remotely pleasant it is not pyridine. Pyridine has a revolting faintly ammoniacal smell and is one of the most unpleasant things I have
smelled in the lab.
If you're not part of the solution, you're part of the precipitate.
|
|
|
zed
International Hazard
Posts: 2283
Registered: 6-9-2008
Location: Great State of Jefferson, City of Portland
Member Is Offline
Mood: Semi-repentant Sith Lord
|
|
Pyridine smells like strongly rancid butt, in a bad way.
Make yerself a little from Nicotinic Acid. It's special.
https://www.youtube.com/watch?v=FNsqYwzm40M
[Edited on 13-12-2017 by zed]
|
|
|
mysteriusbhoice
Hazard to Others
Posts: 477
Registered: 27-1-2016
Member Is Offline
Mood: Became chemistry catboy Vtuber Nyaa
|
|
im gonna guess but maybe it is benzaldehyde or something.
that usually has a sweet smell and is one common solvent used so perhaps they mislabeled it and sold it to you.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
