NoFumeHood Guy
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Sodium metatungstate
Hello everyone!
Not very long ago I saw a fairly interesting ion: [H2W12O40]6-. I tried searching all over the internet, but couldn't find any relatable method of
preparing this compound. Has anyone here tried synthesising it? Is it possible to use [WO4]2- as a reagent?
[Edited on 19-10-2024 by NoFumeHood Guy]
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Precipitates
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Hi!
This paper, and its references, is perhaps a good starting point:
Solid state chemistry of polytungstic acids and their salts.
In summary, and probably massively over-simplifying:
Electrolyse a sodium tungstate solution, and then add a chloride salt to get the metatungstate you desire.
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Bedlasky
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Here ammonium paratungstate on the page 1713
https://library.sciencemadness.org/library/books/brauer_ocr....
Plus you can find this table useful:
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