mewrox99
Hazard to Others
Posts: 321
Registered: 7-6-2010
Location: New Zealand
Member Is Offline
Mood: No Mood
|
|
Synthesis of BaO2 from Ba(NO3)2
Hi.
Is it possible to make Barium Peroxide from Barium Nitrate.
I can make Barium Oxide by the Barium Nitrate to decomposition.
The question is how do I make Barium Peroxide from Barium Oxide. I have 3% H2O2, but can get some 30% if needed.
Thanks.
|
|
|
not_important
International Hazard
Posts: 3873
Registered: 21-7-2006
Member Is Offline
Mood: No Mood
|
|
For anhydrous BaO2 you want the first half of the Brin process, passing dry CO2-free air over BaO at 600 C and 2 bar pressure. See attachment
For the hydrated peroxide go download the book here http://www.archive.org/details/introductiontoc00dunlgoog and read page 33.
Attachment: Brin Process.pdf (460kB)
This file has been downloaded 960 times
|
|
|
Engager
Hazard to Others
Posts: 295
Registered: 8-1-2006
Location: Moscow, Russia
Member Is Offline
Mood: Lagrangian
|
|
Quote: Originally posted by mewrox99  | Hi.
Is it possible to make Barium Peroxide from Barium Nitrate.
I can make Barium Oxide by the Barium Nitrate to decomposition.
The question is how do I make Barium Peroxide from Barium Oxide. I have 3% H2O2, but can get some 30% if needed.
Thanks. |
Hydrated peroxide can be easily produced by adding 30% hydrogen peroxide to fairly concentrated barium nitrate solution. It has low solubility in cold
water (~0.1) and can be easily separated by filtration. Anhydrous peroxide may be obtained by heating - it looses 8 molecules of it's crystalline
water at ~100C.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
