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Author: Subject: Synthesis of thioacetone?
Fery
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[*] posted on 9-1-2024 at 21:19


Thx for sharing the video. I have little of that reagent and also P4S10 and anisole if more needed.
Sulfur compounds are not always stinky. The trithioacetone has a scent of tropical fruits (if you manage to produce it pure from gem 2,2-propanedithiol). Another good scenting thiol is grapefruit mercaptan (perhaps starting from limonene -> ??? alpha terpineol ??? or via another intermediate ???).
Here they used another routes for the grapefruit:
https://sci-hub.ee/10.1002/hlca.19820650614
https://sci-hub.ee/10.1002/pca.2800060506
But I not sure whether you need R or S limonene as the grapefruit thiol is only one of the isomers, but very likely R limonene (orange oil).
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