deadrush
Harmless
Posts: 22
Registered: 3-3-2014
Location: Worcester MA
Member Is Offline
Mood: Fungible
|
|
Glycolic acid + HCl -> Chloroacetic acid
I've read this is possible from a few sources and a patent. It doesnt seem likely to work. Anyone ever done this successfully?
I assume it will require some sort of catalyst.
Later today im going to try glycolic + NaOH -> Sodium Glycolate. Then sodium glycolate + HCl -> sodium chloroacetate. If successful I'd acidify.
Thanks in advance!
|
|
DraconicAcid
International Hazard
Posts: 4355
Registered: 1-2-2013
Location: The tiniest college campus ever....
Member Is Offline
Mood: Semi-victorious.
|
|
You think sodium glycolate is going to react with hydrochloric acid to give sodium chloroacetate instead of glycolic acid?
What is your reasoning behind this?
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
|
|
deadrush
Harmless
Posts: 22
Registered: 3-3-2014
Location: Worcester MA
Member Is Offline
Mood: Fungible
|
|
I know this isnt really a source but it is what gave me the idea initially.
Apparently it does work in reverse according to sciencemadness!
(2nd link below)
ChemicalAid
https://www.chemicalaid.com › tools
C2H3NaO3 + HCl = C2H2NaO2Cl + H2O - Chemical Equation Balancer
https://www.sciencemadness.org/smwiki/index.php/Chloroacetic...
I know i found one other reference to this in a chinese patent. They required the use of a very differnt, complex, and impossible for home catalyst.
|
|
Fery
International Hazard
Posts: 1026
Registered: 27-8-2019
Location: Czechoslovakia
Member Is Offline
|
|
Some people synthesized it from acetic acid with sulfur and bubbling there Cl2 gas. S reacts with Cl2 into chlorinating agents S2Cl2, SCl2. There
could be also an intermediate acetyl chloride and its further chlorination gives chloroacetyl chloride which hydrolyzes with water into chloroacetic
acid.
I was able to find these videos:
https://www.youtube.com/watch?v=SpDtuK9BBBw
https://www.youtube.com/watch?v=NcEQUsrMvx8
https://www.youtube.com/watch?v=UEzmipxWXVc
|
|
brubei
Hazard to Others
Posts: 188
Registered: 8-3-2015
Location: France
Member Is Offline
Mood: No Mood
|
|
hi everyone today's vidéo is sponsorized by the DEA
I'm French so excuse my language
|
|
Texium
Administrator
Posts: 4618
Registered: 11-1-2014
Location: Salt Lake City
Member Is Online
Mood: PhD candidate!
|
|
Balancing an equation doesn’t mean it’s even remotely possible. Next time you start a thread claiming you have “a few sources” without being
able to provide said sources, I’m sending it right to detritus. Scientific discourse doesn’t begin with “so I heard somewhere…”
|
|
Texium
|
Thread Moved 30-12-2023 at 06:54 |