Keras
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Usage of potassium chlorate in organic chemistry
Folks,
it is known that potassium chlorate is a strong oxidising agent, much like potassium permanganate. However, contrarily to the latter, potassium
chlorate seems to be very seldom used in organic chemistry – albeit it leaves behind benign products, essentially potassium chloride.
Does anyone ever attempted an oxidation reaction using potassium chlorate, say, instead of potassium permanganate (ex: toluene → benzaldehyde or
benzoic acid)?
Just curious.
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Pumukli
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Maybe it oxidizes chloride back to chlorine. Then chlorine makes various chlorinated (substituted) products as well. So chlorate may not be as clean
as it seems at first.
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Fery
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http://www.orgsyn.org/demo.aspx?prep=CV2P0553
http://www.orgsyn.org/demo.aspx?prep=CV3P0042
http://www.orgsyn.org/demo.aspx?prep=CV2P0128
[Edited on 1-7-2023 by Fery]
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kmno4
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| Quote: | Maybe it oxidizes chloride back to chlorine. Then chlorine makes various chlorinated (substituted) products as well. So chlorate may not be as clean
as it seems at first.
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Right.
(see for example: Bull. Korean Chem. Soc. 2011, Vol. 32, No. 2, p.472 - freely available... but attached)
[Edited on 1-7-2023 by kmno4]
Attachment: B110219_472.pdf (150kB)
This file has been downloaded 237 times
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