rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
magnesium aluminate refractory up to 1800C.
I need refractory that withstand at least 1800C to make microwave kiln but the fire clay that i have only can handle up to 1400C. i can increase its
up t 1700C by adding Al2O3 but not good enough. MgO is good up to 2500C but need precalcining MgCO3 at 750C to make MgO and another at 1500C to make
dead burnt MgO so there i a chicken and the egg problem. then i learned about Spinel type of gemstone. It has the formula MgAl2O4 and melt about
2135°C.wiki
Attachment: MgAl2O4.pdf (847kB)
This file has been downloaded 825 times
to make the material at convenience i decided to use one pot precipitation of amorphous stuff form MgSO4 and NaAlO2 solution mixed till pH of 7.0 if
possible. NaAlO2 is from reacting Al dross form casting with diluted NaOH so slower the reaction and the excess water will boil away. after solid
stuff is settled decanting the resulting Na2SO4 and keeping it so by adding hydrated lime i can recycle the NaOH. the powder paste at bottom is washed
thoroughly with warm water and dried. resulting powder is heated to 750C or more to get the final product.
i will upload the pics within few weeks because my kiln needs repairing and my order still in progress.
"A mind is a terrible thing to lose"-Meisner
|
|
|
unionised
International Hazard
Posts: 5128
Registered: 1-11-2003
Location: UK
Member Is Offline
Mood: No Mood
|
|
If you use MgCl2 and AlCl3 solutions with excess ammonia to produce the mixed oxide/ hydroxide then you won't have to remove sodium and sulphate
before calcining it.
The NH4Cl will evaporate.
You will get a higher purity product and that should mean a higher melting point.
You can get the chlorides by dissolving the metals (or hydroxides/ carbonates whatever) in aqueous HCl
As an interesting variant you could see if you can use solutions of the citrates in citric acid/ water.
You can coat a substrate with that and then burn off the organics to leave the mixed oxides.
|
|
|
wg48temp9
National Hazard
Posts: 786
Registered: 30-12-2018
Location: not so United Kingdom
Member Is Offline
|
|
If you are going to coat the refractory with a microwave absorber to form the heating element, what do you intend to use as the absorber ?
I am wg48 but not on my usual pc hence the temp handle.
Thank goodness for Fleming and the fungi.
Old codger' lives matters, wear a mask and help save them.
Be aware of demagoguery, keep your frontal lobes fully engaged.
I don't know who invented mRNA vaccines but they should get a fancy medal and I hope they made a shed load of money from it.
|
|
|
rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
Quote: Originally posted by wg48temp9  | | If you are going to coat the refractory with a microwave absorber to form the heating element, what do you intend to use as the absorber ?
|
SiC can up to 1600C.
| Quote: Originally posted by unionised | If you use MgCl2 and AlCl3 solutions with excess ammonia to produce the mixed oxide/ hydroxide then you won't have to remove sodium and sulphate
before calcining it.
The NH4Cl will evaporate.
You will get a higher purity product and that should mean a higher melting point.
You can get the chlorides by dissolving the metals (or hydroxides/ carbonates whatever) in aqueous HCl
As an interesting variant you could see if you can use solutions of the citrates in citric acid/ water.
You can coat a substrate with that and then burn off the organics to leave the mixed oxides.
|
my point was to do it with thing that are easy to find like MgSO4 from bath salt or fertilizer and NaOH from hardware store and Al from scrap. plus
NH4OH is toxic and smelly also residual ammonium chloride is bad for the heating element as it corrosive. and i have to go to a water treatment
supply to get poly aluminum chloride and chemical shop to get MgCl2 in this current time.
"A mind is a terrible thing to lose"-Meisner
|
|
|
yobbo II
National Hazard
Posts: 765
Registered: 28-3-2016
Member Is Offline
Mood: No Mood
|
|
You can purchase alumina bricks for this. They are very expensive. I believe that the alumina must be very pure and that makes them expensive.
Yob
|
|
|
Twospoons
International Hazard
Posts: 1326
Registered: 26-7-2004
Location: Middle Earth
Member Is Offline
Mood: A trace of hope...
|
|
You will want to remove as much sodium as possible - any residue may act as a flux.
Helicopter: "helico" -> spiral, "pter" -> with wings
|
|
|
unionised
International Hazard
Posts: 5128
Registered: 1-11-2003
Location: UK
Member Is Offline
Mood: No Mood
|
|
... or not add it in the first place....
|
|
|
rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
even so called high alumina bricks have Na impurity because of Bayer process.I think 50C water will remove most of Na+.
"A mind is a terrible thing to lose"-Meisner
|
|
|
wg48temp9
National Hazard
Posts: 786
Registered: 30-12-2018
Location: not so United Kingdom
Member Is Offline
|
|
My understanding is the absorption of microwaves by silicon carbide is dependent on its purity and the type of impurity. I tried about 0.1g of my
powdered silicon carbide spread out on the base of a ceramic mug in an empty 800W microwave oven. It did not get noticeably hot to the touch after
40s.
I suggest you try your silicon carbide first.
I am wg48 but not on my usual pc hence the temp handle.
Thank goodness for Fleming and the fungi.
Old codger' lives matters, wear a mask and help save them.
Be aware of demagoguery, keep your frontal lobes fully engaged.
I don't know who invented mRNA vaccines but they should get a fancy medal and I hope they made a shed load of money from it.
|
|
|
rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
| Quote: Originally posted by wg48temp9 |
My understanding is the absorption of microwaves by silicon carbide is dependent on its purity and the type of impurity. I tried about 0.1g of my
powdered silicon carbide spread out on the base of a ceramic mug in an empty 800W microwave oven. It did not get noticeably hot to the touch after
40s.
I suggest you try your silicon carbide first. |
@wg48temp9 no wonder. at high-temperature dielectric loss increases,
which derives from the combined effect of the polarization
relaxation and the electric conductance of SiC. The microwave
absorption demonstrates that SiC powders enhanced microwave
absorption coupled with improved broadband absorption, specifically increased microwave absorption properties at higher temperature.
"A mind is a terrible thing to lose"-Meisner
|
|
|
unionised
International Hazard
Posts: 5128
Registered: 1-11-2003
Location: UK
Member Is Offline
Mood: No Mood
|
|
Unless it's present as this
https://authors.library.caltech.edu/5456/1/hrst.mit.edu/hrs/...
|
|
|
rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
https://en.wikipedia.org/wiki/Beta-alumina_solid_electrolyte
"A mind is a terrible thing to lose"-Meisner
|
|
|
wg48temp9
National Hazard
Posts: 786
Registered: 30-12-2018
Location: not so United Kingdom
Member Is Offline
|
|
So I decided to try a small pile of my 400 mesh silicon carbide between two wires connected to about 2,000Vrms (HT of a MOT with the HT winding of
an other MOT as a ballast. No noticeable conduction uless the wires wire touched and then separated by about 5mm which was probably just an arc drawn
out.
So my silicon carbide is high resistance.
However I did notice a curious effect. A cloud of silicon carbide dust appeared above the high voltage wire (the other wire was at earth voltage). It
looked like it was suspended by the high AC voltage. If the wires touched, shorting out the voltage, the dust dropped down.
I am wg48 but not on my usual pc hence the temp handle.
Thank goodness for Fleming and the fungi.
Old codger' lives matters, wear a mask and help save them.
Be aware of demagoguery, keep your frontal lobes fully engaged.
I don't know who invented mRNA vaccines but they should get a fancy medal and I hope they made a shed load of money from it.
|
|
|
macckone
Dispenser of practical lab wisdom
Posts: 2168
Registered: 1-3-2013
Location: Over a mile high
Member Is Offline
Mood: Electrical
|
|
If you want to use clay, you can use the clay you have then add powdered mullite.
You are going to want to add aluminum hydroxide and mullite and then work the clay until it is fully consistent.
Other methods, get a fire brick of the appropriate temperature and cut a hole in it and line it with graphite powder.
Buy one, $42 on amazon: https://www.amazon.com/Large-Microwave-Kiln-Glass-Fusing/dp/...
Use sorel cement and put it in a charcoal furnace to fuse it and drive off the HCl.
A charcoal furnace will also work to calcine magnesium oxide.
Final method, phosphate bonded refractory, you can use magnesia. It doesn't need to be fully calcined. You basically add phosphoric acid to a wet
paste, there needs to be some magnesium hydroxide present to complete the reaction.
Aluminum oxide also works but the maximum recommended working temperature is below 1800C.
One of the questions is does the whole contraption reach 1800C, because if it is just the area in contact with the graphite, then you can probably use
a lower melting point for the majority, paint on milk of magnesia and then a mix of graphite and magnesia. It will calcine in situ, I haven't tried
it using this method because I am a fan of sorel and I can put it on the BBQ pit. Magnesium Oxychloride will calcine completely at 500C with the
evolution of a LOT of HCl.
Do that part outside in a BBQ pit on a windy day.
|
|
|
RogueRose
International Hazard
Posts: 1596
Registered: 16-6-2014
Member Is Offline
|
|
I'm thinking you could use plasma arc to heat the MgO. Get a few carbon rods and some 6-12v batteries or some good power supplies and then pile up
some MgO around the arc and heat it up. I would think this might be the easiest way to get the temp you are looking for. Another idea is to
maybe use a clay/terrocatta pot and put the MgO inside that.
|
|
|
densest
Hazard to Others
Posts: 359
Registered: 1-10-2005
Location: in the lehr
Member Is Offline
Mood: slowly warming to strain point
|
|
You can buy refractory coatings & sprays. Highest I've used is ZrO for 1800C. Worked pretty well to protect graphite from air at red heat. There
are lots of formulations for different atmospheres and substrates. The manufacturers' data sheets brag about particle size control and proprietary
binders.
Out of curiosity what are you melting at 2500C?
|
|
|
rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
| Quote: Originally posted by densest | You can buy refractory coatings & sprays. Highest I've used is ZrO for 1800C. Worked pretty well to protect graphite from air at red heat. There
are lots of formulations for different atmospheres and substrates. The manufacturers' data sheets brag about particle size control and proprietary
binders.
Out of curiosity what are you melting at 2500C? |
only up to 1800c or so for a induction heater .I'm gonna give it a go with making iron alloys, but I still need to build one first. getting component
is hard and also not enough spare time.
"A mind is a terrible thing to lose"-Meisner
|
|
|
WGTR
National Hazard
Posts: 971
Registered: 29-9-2013
Location: Online
Member Is Offline
Mood: Outline
|
|
I will reiterate the point that macckone made.
High temperature refractory materials are generally not insulative the way that the lower temperature ones are. However, there’s only 400 degrees
difference between 1800C and 1400C. The refractory material only needs to be thick and insulative enough that the “cold” side of if is no higher
than 1400C when it is surrounded by the 1400C firebrick.
|
|
|
rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
| Quote: Originally posted by WGTR | I will reiterate the point that macckone made.
High temperature refractory materials are generally not insulative the way that the lower temperature ones are. However, there’s only 400 degrees
difference between 1800C and 1400C. The refractory material only needs to be thick and insulative enough that the “cold” side of if is no higher
than 1400C when it is surrounded by the 1400C firebrick. |
the walls must be thin for high temperature crucibles and it's insulation, otherwise they tend to crack because of different thermal expansion at
different temperatures .so it's better to use insulating wool for 1400C and insulating powder in between the crucible insulation (crucible sleeve) and
that.
"A mind is a terrible thing to lose"-Meisner
|
|
|
Mateo_swe
National Hazard
Posts: 548
Registered: 24-8-2019
Location: Within EU
Member Is Offline
|
|
I saw a video of a guy making a microwave kiln using silicon carbide grit size F80.
He used waterglass as a binder for the silicon carbide grit and made a 4mm thick ring used as the walls for the microwave kiln.
He then added ceramic wool around the outside of the silicon carbide ring and sprayed it with waterglass.
Maybe waterglass cant be used as a binder for the silicon carbide in your application as you want so high temperatures but maybe something else can be
used as the binder, something that can handle the temps.
The silicon carbide seems to absorb the heat making it a good material for microwave kilns and it melts at 2830°C.
Here is a link to the video i stubled upon a while ago with the guy making a microwave kiln.
https://www.youtube.com/watch?v=rAIyLWEKt8U
I dont know if it can be of any help but the creating of the silicon carbide ring was interesting.
|
|
|
Texium
|
Thread Moved
29-11-2023 at 20:50 |
![[*]](images/xpblue/default_icon.gif){kind=icon}
