symboom
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Transition metal hypochlorites
This are my results
Sodium hypochlorite and magnesium sulfate
Magnesium hypochlorite
Sodium hypochlorite and chromium sulfate
Sodium chomate
Sodium hypochlorite and manganese sulfate
MnO2 and oxygen
Sodium hypochlorite and cobalt nitrate
CoO2 and oxygen
Sodium hypochlorite and nickel sulfate
NiO2 and oxygen
Sodium hypochlorite and copper sulfate
Copper oxychloride
Copper oxychloride and ammonia
Tetramine copper chloride
Urea and copper oxychloride
Copper hydrazine chloride
Ammonium sulfate and copper oxychloride
Hydrazine sulfate
Ammonium hydroxide and zinc oxychloride
Diamine zinc chloride
Urea and zinc oxychloride
Zinc hydrazine chloride
Ammonium sulfate and zinc oxychloride
Hydrazine sulfate
Ammonium sulfate and sodium hypochlorite
Hydrazine sulfate
Aluminum sulfate and sodium hypochlorite
Aluminum hypochlorite decomposes to Cl2
Forms Al2O3 percipitate.
[Edited on 15-7-2018 by symboom]
[Edited on 15-7-2018 by symboom]
[Edited on 15-7-2018 by symboom]
[Edited on 15-7-2018 by symboom]
[Edited on 15-7-2018 by symboom]
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MöbiusMan
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Impressive!
If chemistry was easy it would be called biology.
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XeonTheMGPony
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Again list is useless on its own ! why do you spam this forum with these useless lists, what procedure, (Sodium hypochlorite and manganese sulfate
MnO2 and oxygen; Sodium hypochlorite and zinc sulfate Zinc oxychloride) where did the sulfur go?,
What is the point.
Your not a troll, but yet you spam?! WHY?
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symboom
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Im not trying to spam im tring to add more information of compounds that one can not find easily also is the reason i put it in beginnings. Aluminum
hypochlorite such as says it is unstable other than that it doesnt say it decomposes to chlorine didnt expect that these are all experiments i have
done.
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XeonTheMGPony
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but with out detailed info and work up it is utterly worthless and adds NO info at all. You literally may as well post screen shots of the local phone
book.
The 5 W's (Who, what, where, when, & Why) unless at least 4 is answered it is wasted space!
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AJKOER
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The details on the decomposition products for the unstable hypochlorites (assuming that the some transition hypochlorites were, in particular,
created) appears to be accurate per my recollection.
I would suggest adding a link to each hypochlorite (even if from a dated source like Mellor,...) for those interested in more details. For example,
per my recollection, aluminum hypochlorite exists and was in commercial use (perhaps implying some stability). However, upon application to say a
fabric, it decomposes depositing Al2O3 into the fabric (see https://books.google.com/books?id=RaFIAAAAMAAJ&pg=RA2-PA... ). Note, NaOCl similarly decomposes in contact with organics, producing O2 and
NaCl.
Copper hypochlorite may exist (see https://www.sciencedirect.com/science/article/pii/S004040391... ) but soon breaks down as you noted. Not sure about the existent of the unstable
zinc hypochlorite (see https://www.sciencedirect.com/sdfe/pdf/download/eid/1-s2.0-S... ).
Also missing from your list is the very unstable lead hypochlorite (see http://global.oup.com/uk/orc/chemistry/ichem6e/student/video... and video) and silver hypochlorite (see http://silver.atomistry.com/silver_hypochlorite.html ). Apparently, AgOCl, barring the presence of Ag2O (or AgOH), rapidly breaks down into a
white AgCl precipitate leaving aqueous AgClO3.
Other noble metal hypochlorites (like gold, AuClO) may exist (not certain).
[Edited on 16-7-2018 by AJKOER]
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j_sum1
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Thread Pruned 15-7-2018 at 14:44 |