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Author: Subject: sodium methanetetracarboxylate
morsagh
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[*] posted on 26-5-2015 at 11:27
sodium methanetetracarboxylate


Anybody has some ideas how to make sodium methanetetracarboxylate without using pentaerythritol? Maybe oxidation of 2,2,4-trimethylpentane?
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clearly_not_atara
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[*] posted on 26-5-2015 at 11:52


A couple of Mannich additions w/formaldehyde and NH3 to diethyl malonate followed by oxidation of the resulting 2,2-di(ethoxycarbonyl)-1,3-propanediamine should generate the desired compound.
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Metacelsus
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[*] posted on 26-5-2015 at 18:54


It would probably be easier to make your own pentaerythritol, depending on availability of acetaldehyde.

(http://www.orgsyn.org/demo.aspx?prep=CV1P0425)




As below, so above.

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[*] posted on 27-5-2015 at 02:23


oxidation of pinacolone by KMnO4 doesn´t work?
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Nicodem
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