bismuthate
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The reaction question thread.
I thought it would be nice to have a thread where people can ask how does ******** react with ********. So I'll start off.
NaNH2+PH3==>NaPH2+NH3?
2Na+2PH3==>2NaPH2+H2?
3NaNO3+AsCl3==>As(NO3)3+3NaCl?
[Edited on 7-12-2013 by bismuthate]
[Edited on 7-12-2013 by bismuthate]
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Random
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Many reactions are possible but another question is under what conditions.
For example hydrogen and ammonia looks simple on paper until you see actual pressure and heat required.
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bismuthate
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Yeah it would be nice if people added in under what conditions they react, but this is just a question of how a reaction proceeds.
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Zyklon-A
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I was wondering if barium nitrate could react with potassium perchlorate to make barium perchlorate and potassium nitrate.
Solubility of perchlorate is 66.48 g/100 mL (25 °C), While potassium perchlorate is only 1.5 g/100 mL (25 °C).
I think it wont work actually, just looking at the solubility data.
Can anyone provide a professional opinion on the subject?
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mnick12
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Quote: Originally posted by Zyklonb  | I was wondering if barium nitrate could react with potassium perchlorate to make barium perchlorate and potassium nitrate.
Solubility of perchlorate is 66.48 g/100 mL (25 °C), While potassium perchlorate is only 1.5 g/100 mL (25 °C).
I think it wont work actually, just looking at the solubility data.
Can anyone provide a professional opinion on the subject? |
Indeed the poor solubility of potassium perchlorate indicates that the equilibrium highly favors KClO4 over Ba(ClO4)2. Potassium perchlorate is kind
of a dead end for making other perchlorates. Sodium perchlorate or would be a better option, however if the intended use is pyrotechnic applications
removing all the sodium ions could be very difficult. I would start with ammonium perchlorate, although it is more expensive.
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Zyklon-A
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Ammonium perchlorate is generally made from perchloric acid.
| Quote: |
.......however if the intended use is pyrotechnic applications...... |
No, I'll be using it to make perchloric acid, according to this reaction: Ba(ClO4)2 (aq) + H2SO4-->
BaSO4 (s) + HClO4 (aq).
I guess I can find another method to make barium chlorate.
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DraconicAcid
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| Quote: | I thought it would be nice to have a thread where people can ask how does ******** react with ********. So I'll start off.
NaNH2+PH3==>NaPH2+NH3? |
It should. Phosphine will be a stronger acid than ammonia. Nasty stuff to work with, though.
| Quote: | | 2Na+2PH3==>2NaPH2+H2? |
It should. I know that triphenylphosphine will react with sodium to give NaPPh2 and NaPh (which was protonated under the reaction conditions, but I
don't recall what they were).
| Quote: | | 3NaNO3+AsCl3==>As(NO3)3+3NaCl? |
I doubt it. The arsenic-chlorine bond has significant covalent character, and I wouldn't expect the nitrate to bond as strongly.
[Edited on 6-3-2014 by DraconicAcid]
[Edited on 6-3-2014 by DraconicAcid]
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
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