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plante1999
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[*] posted on 8-2-2011 at 15:07
Ti4O7 anode

hi!!

i was thinking about Ti4O7 plated on ti rod

the processe i was thinking: take very pur ti rod and oxidise it in sulfuric acid electrochemicaly , take a test tube with a glass stopper with 2 hole one hole with H2 intry and another with escaping H2O , the botom of the test tube with some tin or lead with the uncoated place of the rod will be droped , the anode will be heated at 1000 degree c for 1 hour with H2 flow and than electrolised in brine.

thanks!


my reference is to big to be posted so i will try anoter time.





[Edited on 8-2-2011 by plante1999]

[Edited on 8-2-2011 by plante1999]

[Edited on 8-2-2011 by plante1999]
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dann2
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[*] posted on 11-2-2011 at 15:06


What is the Anode going to be making long term?
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plante1999
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[*] posted on 15-2-2011 at 14:32


sorry for the double post.

here the document:


<a href=http://www.filedropper.com/hayfieldpcsdevelopmentofanewmaterial-monolithicti4o7ebonexceramicrsc20010854049843><img src=http://www.filedropper.com/download_button.png width=127 height=145 border=0/></a><br /> <div style=font-size:9px;font-family:Arial, Helvetica, sans-serif;width:127px;font-color:#44a854;> <a href=http://www.filedropper.com >file storage</a></div>

[Edited on 15-2-2011 by plante1999]
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Zaratukhshthra
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[*] posted on 18-2-2011 at 00:39


I doubt it could work, using Ti4O7 as anode will most probably oxidize it to (insulator) TiO2.
something like: Ti4O7 + H2O => 4TiO2 + 2H+ + 2e-
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plante1999
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[*] posted on 18-2-2011 at 05:12


in fact this type of anode is used in manifature of chlorine (reference is up this message).
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Tinamics
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[*] posted on 8-3-2011 at 23:56


We are the producer of Ti4O7 ceramic powder. Please contact jayhuang118@126.com

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