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Author: Subject: Preparing Chloramines without formation of the H2N-NH2 compound?
RareEarth
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[*] posted on 29-4-2015 at 15:51
Preparing Chloramines without formation of the H2N-NH2 compound?


I was planning to try to make some substituted chloramines with sodium hypochlorite (bleach), and I wanted to minimize the the formation of the hydrazine-like compound. How realistically can this performed? If it is possible, what kind of reaction parameters should I control?
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Metacelsus
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[*] posted on 29-4-2015 at 16:20


Is your starting amine primary or secondary? If it's secondary, making sure hypochlorite is always in excess should do the trick. (This wouldn't work with primary amines, because dichloroamines could form).



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RareEarth
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[*] posted on 29-4-2015 at 16:30


Yes it would be a secondary amine. Are you saying that the hydrazine-type compound is difficult to form under these circumstances?
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Nicodem
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