stygian
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This could be useful... new ketene prep?
Just stumbled across this pdf.
http://www.dupont.com/dms/docs/DMS_PUSH_Bulletin.pdf
Claims that dimethyl sulfate catalyses pyrolysis of methyl acetate into ketene. I don't think I've seen this mentioned before, so, it is done.
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CherrieBaby
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The reference they give for this is:
K.K. Georgieff, Can. J. Chem., 30, 322 (1952).
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