organosurf
Harmless
Posts: 8
Registered: 11-12-2012
Member Is Offline
Mood: No Mood
|
|
Zinc / HCl reduction
Does anyone know the exact reaction conditions ( proportion of reactants, conc of acid, eq of Zn, etc ) and especially yields for the above to reduce
an aliphatic primary halide ( R-Cl ) to its alkane ?
Though there is a lot of mention of this reaction on the web, there are absolutely no detailed reaction conditions given anywhere. Have checked far
and wide, just got one ref that gave a measly yield of 12%.
How about using Aluminum with acid for such reductions ? There is no mention of this anywhere.......
|
|
|
Nicodem
|
Thread Moved
4-3-2014 at 09:23 |
Metacelsus
International Hazard
Posts: 2539
Registered: 26-12-2012
Location: Boston, MA
Member Is Offline
Mood: Double, double, toil and trouble
|
|
I know the zinc-copper couple will do it, but I've never heard of just plain zinc being used.
|
|
|
Random
International Hazard
Posts: 1120
Registered: 7-5-2010
Location: In ur closet
Member Is Offline
Mood: Energetic
|
|
Read the thread about nascent hydrogen here. Ig will give you few answers on mechanisms.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
