ElectroWin
Hazard to Others
Posts: 224
Registered: 5-3-2011
Member Is Offline
Mood: No Mood
|
|
Upsalite ? pure MgCO3
i was just reading about Upsalite, a recently synthesized zeolite with some surprising properties..
http://banoosh.com/blog/2013/08/15/scientists-make-impossibl...
http://en.wikipedia.org/wiki/Upsalite
|
|
bfesser
Resident Wikipedian
Posts: 2114
Registered: 29-1-2008
Member Is Offline
Mood: No Mood
|
|
I, for one, am very excited. This seems well suited to amateur experimentation.
|
|
Fantasma4500
International Hazard
Posts: 1681
Registered: 12-12-2012
Location: Dysrope (aka europe)
Member Is Offline
Mood: dangerously practical
|
|
magnesium oxide (MgO) and carbon dioxide (CO2), dissolved in methanol, a common industrial solvent. The result is pure, dry MgCO3.
this would mean that you would be able to dissolve Al or Al2O3 to form CO2 in solution, as methanol reacts with one of them, not sure at all if it was
Al2O3 or actual Al metal
anyhow, then you can get to make CO2 in the solution using methanol and perhaps al foil
i would suggest putting MgO on a piece of cloth
then in a beaker of MeOH you fill the bottom with al foil folded hard together or whatever
then you put the MgO down, so its on top of the aluminium foil, perhaps a sieve of some sort?
the CO2 has to get in contact with the MgO, i suppose
very interesting, sounds like more than just do-able
biggest problem would be to get MgO in decent amounts, magnesium is a waste to burn off to get MgO
|
|
bfesser
Resident Wikipedian
Posts: 2114
Registered: 29-1-2008
Member Is Offline
Mood: No Mood
|
|
<strong>Antiswat</strong>, I can't make sense of your reply. Why are you talking about aluminium?
Also, I think it would be interesting to explore the science—not really concerned with an economical synthesis. However, if you prefer, MgO
could be purchased, rather than prepared by burning Mg.
Hooray! They published the paper for free, online:
<strong><a href="http://www.plosone.org/article/fetchObject.action?uri=info%3Adoi%2F10.1371%2Fjournal.pone.0068486&representation=PDF"
target="_blank">A Template-Free, Ultra-Adsorbing, High Surface Area Carbonate Nanostructure</a></strong> <img
src="../scipics/_pdf.png" />
Quote: | <div align="center"><img
src="http://www.plosone.org/article/fetchObject.action?uri=info:doi/10.1371/journal.pone.0068486.g002&representation=PNG_M" /></div>
<strong>Figure 2. Synthesis of Upsalite. i)</strong> In the first step MgO (s) is mixed with methanol under 3 bar
CO<sub>2</sub> pressure at 50°C. <strong>ii)</strong> After 2.5 h the HOMgOCH<sub>3</sub> is formed in the
solution, the pressure is lowered to 1 bar and the heating is turned off. At the same time the methanol reacts with the CO<sub>2</sub> and
forms CH<sub>3</sub>OCOOH (methyl hemicarbonic acid). <strong>iii)</strong> HOMgOCH<sub>3</sub> reacts with
CH<sub>3</sub>OCOOH and forms water and H<sub>3</sub>COCOOMgOCH<sub>3</sub> (methyl esther of magnesium methyl
carbonate). At this point the solution changes colour from white to light yellow. <strong>iv)</strong>
H<sub>3</sub>COCOOMgOCH<sub>3</sub> reacts with the water formed in step iii) and forms HOMgOCOOCH<sub>3</sub> (or
MgCO<sub>3</sub>·CH<sub>3</sub>OH) which upon <strong>v)</strong> heating at 70°C releases
CH<sub>3</sub>OH and forms MgCO<sub>3</sub>.
doi:<a href="http://dx.doi.org/10.1371/journal.pone.0068486.g002" target="_blank">10.1371/journal.pone.0068486.g002</a> <img
src="../scipics/_ext.png" />
. . .
Synthesis
In the current work 4 g magnesium MgO powder was placed in a glass bottle together with 60 ml methanol and a stirring magnet. The solution was put
under 3 bar CO<sub>2</sub> pressure and heated to 50°C. After approximately 4 hours the mixture was allowed to cool to RT and the
carbon dioxide pressure was lowered to 1 bar, and the reaction continued until a gel had formed. When a gel was obtained, the carbon dioxide pressure
was removed and the gel was allowed to solidify and dry at ~70°C during 3 days. A schematic description of the synthesis is found in Fig. 2.
– Forsgren J, Frykstrand S, Grandfield K, Mihranyan A, Strømme M (2013) <strong>A Template-Free, Ultra-Adsorbing, High Surface Area
Carbonate Nanostructure.</strong> PLoS ONE 8(7): e68486. doi:<a href="http://dx.doi.org/10.1371/journal.pone.0068486"
target="_blank">10.1371/journal.pone.0068486</a> <img src="../scipics/_ext.png" /> |
[Edited on 16.8.13 by bfesser]
|
|
blogfast25
International Hazard
Posts: 10562
Registered: 3-2-2008
Location: Neverland
Member Is Offline
Mood: No Mood
|
|
He's going by analogy. Al carbonate cannot exist in watery medium but could possibly be synthesised by analogy with MgCO3. Remains to be
proved, of course...
[Edited on 16-8-2013 by blogfast25]
|
|
Fantasma4500
International Hazard
Posts: 1681
Registered: 12-12-2012
Location: Dysrope (aka europe)
Member Is Offline
Mood: dangerously practical
|
|
i was talking about how aluminium could be added to form the CO2, although i recall something about some H2O being formed by CH3OH + Al now, which
might ruin the whole thing.. oh well.. perhaps dessicant would be needed if aluminium was used?
|
|
Metacelsus
International Hazard
Posts: 2539
Registered: 26-12-2012
Location: Boston, MA
Member Is Offline
Mood: Double, double, toil and trouble
|
|
How does aluminum form CO2 from methanol? From Wikipedia, the reaction is:
6 MeOH + 2 Al → 2 Al(MeO)3 + 3 H2
https://en.wikipedia.org/wiki/Methanol
The reaction takes place because MeOH is able to attack the passivization layer around Al, and also because aluminum methoxide is soluble in MeOH.
Neither H2O nor CO2 is formed.
|
|
blogfast25
International Hazard
Posts: 10562
Registered: 3-2-2008
Location: Neverland
Member Is Offline
Mood: No Mood
|
|
There is nothing in that wikilink to suggest direct reaction between methanol and Al is possible. Do you have any real evidence that it is?
http://en.wikipedia.org/wiki/Alkoxide#By_electrochemical_pro...
... is interesting but doesn't discuss aluminium methoxide...
|
|
DraconicAcid
International Hazard
Posts: 4319
Registered: 1-2-2013
Location: The tiniest college campus ever....
Member Is Offline
Mood: Semi-victorious.
|
|
Quote: | At the same time the methanol reacts with the CO<sub>2</sub> and forms CH<sub>3</sub>OCOOH (methyl hemicarbonic acid).
<strong>iii)</strong> HOMgOCH<sub>3</sub> reacts with CH<sub>3</sub>OCOOH and forms water and
H<sub>3</sub>COCOOMgOCH<sub>3</sub> (methyl ester of magnesium methyl carbonate). At this point the solution changes colour
from white to light yellow. |
I find this a dubious mechanism. Direct reaction of the methoxide with carbon dioxide to give the methylcarbonate anion seems a lot more likely than
reaction of methanol with carbon dioxide to give the acid, followed by reaction with the base.
I really doubt that a similar method could be used to give aluminum carbonate, since aluminum oxide is such a thermodynamic sink. Slow reaction of
aluminum methoxide in anhydrous methanol with carbon dioxide to give nice crystals of alumina sounds intriguing, though...
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
|
|
AndersHoveland
Hazard to Other Members, due to repeated speculation and posting of untested highly dangerous procedures!
Posts: 1986
Registered: 2-3-2011
Member Is Offline
Mood: No Mood
|
|
This is very interesting, it appears that methanol saturated with carbon dioxide (under pressure) can dissolve MgO, since the transient methylcarbonic
acid is created. great way to avoid contamination with water, this could be useful for forming other anhydrous magnesium salts
Quote: Originally posted by blogfast25 |
There is nothing in that wikilink to suggest direct reaction between methanol and Al is possible. Do you have any real evidence that it is?
|
It is, I have read about this before. The reaction is very slow, however. Methanol cannot be stored in aluminum fuel tanks for this reason, because it
will eventually corrode and burn a hole.
[Edited on 28-8-2013 by AndersHoveland]
|
|
Metacelsus
International Hazard
Posts: 2539
Registered: 26-12-2012
Location: Boston, MA
Member Is Offline
Mood: Double, double, toil and trouble
|
|
Quote: |
There is nothing in that wikilink to suggest direct reaction between methanol and Al is possible.
|
The article discusses the incompatibilities of methanol with aluminum vehicle parts, and specifically cites the reaction.
https://en.wikipedia.org/wiki/Methanol#Fuel_for_vehicles
[Edited on 28-8-2013 by Cheddite Cheese]
|
|