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Author: Subject: Why is rust more sensitive to acids than pure Fe2O3?
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[*] posted on 24-1-2024 at 10:25
Why is rust more sensitive to acids than pure Fe2O3?


Ordinary brown rust can be removed from a steel plate in no time with citric acid, but pure red Fe2O3 is much tougher. Even hot 75% H3PO4 takes minutes to disolve it. At room temperature it takes at least 8h. Why is that? Same with black Fe3O4 btw.



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[*] posted on 24-1-2024 at 11:08


Because the pure material is calci8ned and generally unreactive.



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[*] posted on 24-1-2024 at 15:47


Fe2O3 prepared under heat has the structure of corundum - the alpha modification of Al2O3, which is insoluble in acids. In general, crystalline substances dissolve much less easily than amorphous or only very finely crystalline substances. In the case of gels precipitated from solutions, how old the gel is also affects solubility; the older it is, the less soluble it is, as the size of its crystals increases at the microscopic level. Thus, in practice, some water-insoluble hydroxide is easily dissolved in acid shortly after its preparation, but cannot be dissolved in the same acid six months later.
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