metalresearcher
National Hazard
Posts: 757
Registered: 7-9-2010
Member Is Offline
Mood: Reactive
|
|
Why is Beryllium so rare ?
Being the fourth element in the periodic table, it one of the rarest elements, particularly so low in the periodic table. Its neighbors are much more
abundant, even the relatively rare lithium. And it is an even element, normally even elements are more abundant than odd elements, like its (odd)
neighbors 3 Li and 5 B.
In stars, where all the elements are created by nucleosynthesis, He fusion does not deliver Be as Be-8 (two He-4 nuclei fused together) because it is
extremely unstable. It rather fuses to C-12.
Why is this ?
|
|
phlogiston
International Hazard
Posts: 1379
Registered: 26-4-2008
Location: Neon Thorium Erbium Lanthanum Neodymium Sulphur
Member Is Offline
Mood: pyrophoric
|
|
I think you've already described the main reason: Be-8 is unstable. As to why -that- is: probably because it can decay in not just one, but two alpha
particles, which are very stable. so, that is an energetically favourable reaction.
-----
"If a rocket goes up, who cares where it comes down, that's not my concern said Wernher von Braun" - Tom Lehrer
|
|
Admagistr
Hazard to Others
Posts: 363
Registered: 4-11-2021
Location: Central Europe
Member Is Offline
Mood: The dreaming alchemist
|
|
The naturally stable beryllium found in minerals and gems is Be-9.But I read in a book by Dr.Josiph Kleczek, who was a famous astronomer and
astrophysicist, that not only Be-8 is unstable but also Be-9 decays rapidly at the very high temperatures found in stars and I think the main decay
product is two helium nuclei.
|
|
violet sin
International Hazard
Posts: 1480
Registered: 2-9-2012
Location: Daydreaming of uraninite...
Member Is Offline
Mood: Good
|
|
Tellurium is rare because of a hydride off gassing during the hot planetary formation IIRC. I wonder if beryllium has a similar cause.
Wikipedia tellurium
"Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium
to be lost to space as a gas during the hot nebular formation of Earth"
|
|
Admagistr
Hazard to Others
Posts: 363
Registered: 4-11-2021
Location: Central Europe
Member Is Offline
Mood: The dreaming alchemist
|
|
Quote: Originally posted by violet sin | Tellurium is rare because of a hydride off gassing during the hot planetary formation IIRC. I wonder if beryllium has a similar cause.
Wikipedia tellurium
"Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium
to be lost to space as a gas during the hot nebular formation of Earth"
|
BeO is volatile at temperatures above 1000 C in the presence of water vapour, which is how it escaped from the magma in the depths of the earth and
formed beryl deposits on the earth's surface in the environment of granite pegmatites. If BeO did not have the property of concentrating in pegmatites
in this way,beryllium would be much less available.Its rarity is similar to that of tin.If hot water steam were to leave the earth's atmosphere under
supervolcanism,a significant amount of beryllium could escape in this way...
|
|
clearly_not_atara
International Hazard
Posts: 2786
Registered: 3-11-2013
Member Is Offline
Mood: Big
|
|
Basically, nucleons have orbitals like electrons. The first orbital has two states, just like with electrons. So helium-4, with 2 and 2, is unusually
stable for a small nucleus. Normally, more nucleons = more stable up to about iron, but beryllium has half its nucleons in the higher kinetic energy
state and that just tips it into instability. Beryllium-8 decays by alpha decay; the next alpha-decay nucleus is tellurium-104!
The orbital numbers for nucleons are not quite the same as electrons, due to complicated symmetry in quantum chromodynamics. The first orbital has
two, then six, then twelve, then eight (!?!?!), then 22... due to relativistic weirdness and non-convergence of QCD diagrams we can't actually predict
the whole series.
https://en.wikipedia.org/wiki/Magic_number_(physics)
[Edited on 11-8-2023 by clearly_not_atara]
|
|
Σldritch
Hazard to Others
Posts: 309
Registered: 22-3-2016
Member Is Offline
Mood: No Mood
|
|
More than the scarcity of Beryllium, the scarcity of Beryllium-7 bothers me. If the isotope were stable, which it is so alluringly close to being, the
metallic element could be had in a 22% lighter form - and it is already the lightest structurally useful metal!
[Edited on 11-8-2023 by Σldritch]
|
|
woelen
Super Administrator
Posts: 8012
Registered: 20-8-2005
Location: Netherlands
Member Is Offline
Mood: interested
|
|
It is scarce, because it is formed in stars, but also quickly is destroyed again. In stellar cores, there is fusion of light elements, and beryllium
is one of the elements, formed in that process, especially in older stars, in which further fusion of helium cores is an important source of its
energy output. But under the conditions in such stellar cores, with helium present in large amounts, it easily is fused further with helium nuclei to
form carbon. So, upon formation, it quickly is reacted further with helium nuclei to make carbon. Carbon on the other hand, does not as easily fuse
with other nuclei, and for this reason, carbon is much more abundant than beryllium. It is this situation, which makes our presence posisble
|
|