rockyit98
Hazard to Others
Posts: 283
Registered: 12-4-2019
Location: The Known Universe
Member Is Offline
Mood: no mood is a good mood
|
|
do alkali carbonate and alkyl halides react to give carbonate esters?
do alkali carbonate and alkyl halides react to give carbonate esters? - Na2CO3 +2(CH3CH2Cl) -------->2NaCl + CH3CH2OCOOCH3CH2
[Edited on 27-7-2019 by rockyit98]
|
|
|
Ubya
International Hazard
Posts: 1247
Registered: 23-11-2017
Location: Rome-Italy
Member Is Offline
Mood: I'm a maddo scientisto!!!
|
|
i don't know, but something is telling me that it is really unlikely, at least in normal conditions
---------------------------------------------------------------------
feel free to correct my grammar, or any mistakes i make
---------------------------------------------------------------------
|
|
|
Boffis
International Hazard
Posts: 1867
Registered: 1-5-2011
Member Is Offline
Mood: No Mood
|
|
You mght be able to do it with silver carbonate and alkyl bromide or iodide
|
|
|
AvBaeyer
National Hazard
Posts: 651
Registered: 25-2-2014
Location: CA
Member Is Offline
Mood: No Mood
|
|
The short answer is no. Alkali metal carbonates (eg, potassium, cesium) are widely used as bases for alkylation with reactive alkyl halides. I have
never seen a report or comment that dialkyl carbonates have been detected or isolated from these reactions.
Boffis's comment that silver carbonate may yield dialkyl carbonates is a sound one and should be searched for further information.
AvB
|
|
|
DraconicAcid
International Hazard
Posts: 4333
Registered: 1-2-2013
Location: The tiniest college campus ever....
Member Is Offline
Mood: Semi-victorious.
|
|
What solvent are you going to dissolve the silver carbonate in? I suspect that you're only going to be able to get that to work in acetonitrile, and
you'd need an iodide to get the silver to precipitate from that solution.
Please remember: "Filtrate" is not a verb.
Write up your lab reports the way your instructor wants them, not the way your ex-instructor wants them.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
