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Author: Subject: how to preparation of nickel citrate??
azarnoosh
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[*] posted on 25-8-2010 at 22:40
how to preparation of nickel citrate??


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bbartlog
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[*] posted on 26-8-2010 at 06:19


Metathesis. Give us a better question and maybe you'll get a better answer. Really this is detritus.
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ScienceSquirrel
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[*] posted on 26-8-2010 at 06:54


Reacting 2 equivalents of citric acid with one of nickel carbonate.
I would expect it to be a bit like iron (II) citrate.
http://en.wikipedia.org/wiki/Iron%28II%29_citrate
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azarnoosh
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[*] posted on 29-8-2010 at 18:38
citrate nickel?how to produce?:(


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mr.crow
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[*] posted on 29-8-2010 at 18:48


Please learn how to communicate properly



Double, double toil and trouble; Fire burn, and caldron bubble
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psychokinetic
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[*] posted on 30-8-2010 at 00:05


US$0.05 + a lemon.

Stir.

Perhaps if you told us what you were using it for, what ways you were interested in making it etc. Ask the right question and you can get more than a great answer, here.




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I was a sorry witness of such doings, knowing that a little theory and calculation would have saved him ninety per cent of his labor.”
-Tesla
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ScienceSquirrel
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[*] posted on 30-8-2010 at 11:38


I have already attempted to answer your question elsewhere.
Iron II forms a stable complex citrate.
Nickel II salts are far more stable to oxidation than iron II salts and I would expect nickel II carbonate to form a similar stable complex on reacting one mole of the carbonate with two moles of citric acid.
Here is the dinickel tricitrate complex which is well known and defined.
http://www.chemicalbook.com/ChemicalProductProperty_EN_CB978...
You have a dibasic metal ion and a tribasic acid that forms complexes very readily, it is pretty obvious that a range of compounds can be formed in which the ratio of nickel atoms to citrate anions varies and may even be non stochiometric!
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