Okaris
Harmless
Posts: 12
Registered: 22-5-2018
Member Is Offline
|
|
Looking for [2,2'-bithiophen]-5-yltrimethyl-stannane
Does anyone know where to buy [2,2'-bithiophen]-5-yltrimethyl-stannane (CAS: 133144-35-1) directly? Can't find it in Sigma-Aldrich. Thanks!
EDIT: Oops. Used the wrong structure. Changed it to reflect the correct one.
[Edited on 14-11-2018 by Okaris]
|
|
|
j_sum1
Administrator
Posts: 6324
Registered: 4-10-2014
Location: At home
Member Is Offline
Mood: Most of the ducks are in a row
|
|
Out of curiosity, what is it useful for?
|
|
|
Boffis
International Hazard
Posts: 1867
Registered: 1-5-2011
Member Is Offline
Mood: No Mood
|
|
The structure image doesn't correspond the the named compound. Its the 4-nitrophenyl rather than the trimethylstannyl derivative.
The answer to your question is no but have you tried TCI International?
[Edited on 13-11-2018 by Boffis]
|
|
|
j_sum1
Administrator
Posts: 6324
Registered: 4-10-2014
Location: At home
Member Is Offline
Mood: Most of the ducks are in a row
|
|
Quote: Originally posted by Boffis  | The structure image doesn't correspond the the named compound. Its the 4-nitrophenyl rather than the trimethylstannyl derivative.
The answer to your question is no but have you tried TCI International?
[Edited on 13-11-2018 by Boffis] |
Good point. I just looked at the picture rather than reading carefully.
Interestingly, I am not seeing its full structure here either. Although is is better represented on this site. What gives?
And I would still like to know what it is used for. Organic tin has always seemed to me to be a mysterious beast.
|
|
|
DJF90
International Hazard
Posts: 2266
Registered: 15-12-2007
Location: At the bench
Member Is Offline
Mood: No Mood
|
|
Searching on eMolecules gives only the bis-stannylated compound as commercially available. You might have better luck making it yourself, either by
selective removal of one tin group, or by starting from bithiophene and proceeding via alpha-lithiation and quenching with R3SnCl
@jsum1 - It'll be used for Pd-catalysed coupling (Stille reaction), probably to make extended pi-systems for optoelectronics-type materials. There has
been a lot in the literature on such systems over the past few years.
[Edited on 13-11-2018 by DJF90]
|
|
|
Okaris
Harmless
Posts: 12
Registered: 22-5-2018
Member Is Offline
|
|
| Quote: Originally posted by DJF90 | Searching on eMolecules gives only the bis-stannylated compound as commercially available. You might have better luck making it yourself, either by
selective removal of one tin group, or by starting from bithiophene and proceeding via alpha-lithiation and quenching with R3SnCl
@jsum1 - It'll be used for Pd-catalysed coupling (Stille reaction), probably to make extended pi-systems for optoelectronics-type materials. There has
been a lot in the literature on such systems over the past few years.
[Edited on 13-11-2018 by DJF90] |
Do you know of any literature where the synthesis of the product is through removal of one tin group or the other one with alpha-lithiation? I've been
searching a few literature sources and all involve overnight reactions. Preferably trying to search for one that can be done within the day.
|
|
|
![[*]](images/xpblue/default_icon.gif){kind=icon}
