Ethyl acetate is nearly impossible to separate from ethanol.
Ethyl acetate has a bp of 77C
Ethanol has a bp of 78C
Yes given enough reflux and enough runs you can get it out but it isn't easy. It is easier to decompose it with sodium carbonate or sodium hydroxide.
If you are making ethyl acetate, the usual method is absolute ethanol and acetic acid over sulfuric acid or sodium bisulfate at reflux with an acid
water scavenger (sulfuric acid acts as a scavenger). |