Sciencemadness Discussion Board

How does enzyme phenylalanine hydroxylase generate tyrosine

kevsim - 13-4-2016 at 13:58

I have been trying to find the following information and had no luck.
Could somebody please explain -

"How does the enzyme phenylalanine hydroxylase generate
tyrosine?"

Also could somebody please explain the following -
What general type of reactions does Ligases catalyse

kevsim

aga - 13-4-2016 at 14:22

Well, i know nothing of biochem at all, yet even I would have to ask :-

"what is phenylalanine hydroxylase generating tyrosine from ?"
and i'd probably get a clue from that.

Edit:

aren't enzyme names given by what they do ?

If so, the 'hydroxylase' part should mean something.

[Edited on 13-4-2016 by aga]

mnick12 - 13-4-2016 at 22:22

Well from 5 minutes of googling it looks like hydroxylation occurs through a Fe(iv)-oxo intermediate which is formed through the cleavage of an Fe(ii) peroxo tetrahydrobipterin intermediate.

Also Ligases, really? Just google it dude we are not doing your hw for you.

clearly_not_atara - 14-4-2016 at 08:00

Hydroxylases in the human body mostly use the same basic idea:

* forming a complex with the target molecule such that the active site is close to an iron atom

* oxidizing said iron atom with peroxide to highly reactive/unstable FeO2+ complex

* oxygen transfer from FeO2+ to the substrate.

The FeO2+ complexes can be generated in vitro very transiently, but modern science has no molecular machinery with which to transport this species to the desired hydroxylation site.

phlogiston - 14-4-2016 at 08:42

ligases connect two molecules together. Probably the most well known ligases are DNA ligases that connect two strands of DNA together and are commonly used as a tool in molecular biological labs.

If we do your homework, will you please promise to just become a mailman or garbage collector, so the rest of us that is willing to make some effort can have the nice jobs and houses with a garage large enough to put our mad scientist lab in?

kevsim - 14-4-2016 at 14:17

I thank you all for the replies.

kevsim