Chem. Abstr. 99: 194170
Photochemical oxidation of triethylamine by hexachloroethane
Zhurnal Organicheskoi Khimii, 1983, 19(7), 1553-1554.
By: Markaryan, Sh. A.
The title reaction gave Et2NCH:CH2 and C2Cl5H. Initially an ion radical pair was formed, and this lost HCl to give a neutral radical pair.
Chem. Abstr. 108: 221256
The photochemical reaction of dialkyl ethers with perchloroalkanes
Armyanskii Khimicheskii Zhurnal, 1987, 40(5), 334-335.
Markaryan, Sh. A.
RCCl3 (R = Cl, Cl3C) reacted with (R1CH2)2O (I; R1 = Me, Pr) in a 1:10 ratio under UV irradn. to give HCl and the corresponding R1CH2OCHClR1 and
RCHCl2 in ≤20% yield via initial C-Cl bond cleavage and radical-chain abstraction of an α-H from I. |