You mean adjust the "emission".
It is possible through these methods I know of:
Pulling - Varying the SWR varies output centre frequency. The curve is usually documented in the spec sheet.
Pushing - Varying the anode voltage/current allows for a limited control of output centre frequency.
Magnetic susceptibility - Varying the impinging magnetic field around the core can also affect output centre.
Cavity tuning - Tricky, but apparently it works. A method of adding cavity-based tuning adjustment to a magnetron designed without said adjustment.
Requires engineering expertise due to the L/C relationships inside each cavity. Basically introduces set-screws into certain cavities.
Even though it is possible, how far did you want to shift the centre frequency? If it's 5Mhz, it is probably practical. If you want
2450->3250, forget it.
Remember you will probably need a spectrum analyser to see what you are doing, otherwise you will have no idea if your fiddling is changing anything.