Sciencemadness Discussion Board

Unknown chemical on Floppy disc's

Chemistry Alchemist - 29-11-2011 at 04:56

I cut up an old floppy disc (the flexible disc inside) and added it to a small bit of HCl... i read somewhere that its Sm, but on the MSDS of Samarium(II) Chloride it says its a pale yellow to white... this is a deep yellow... does anyone know what this could be? The Floppy disc has also gone from a non transparent disc to a bit transparent...

DSC01669.JPG - 90kB

As u can see in the picture the disc is now transparent... so what ever was in the disc has been leached out into solution...

ScienceSquirrel - 29-11-2011 at 05:06

As far as I know the material is iron III oxide based which would account for the yellow colour.

http://en.wikipedia.org/wiki/Floppy_disc#Structure

Arthur Dent - 29-11-2011 at 05:10

It's pretty safe to assume that it will be mostly ferric chloride, since floppies use a similar iron oxide coating on a flexible plastic media like 4-track cassettes, VHS/BETA cartridges and open reel tape.

If there is Samarium in this stuff, it will probably be in minute quantities, but I doubt it, because the magnetic properties of Samarium and Cobalt together make them more appropriate for actual magnets.

You are more likely to find some Chromium Oxide, that was used many years ago to improve the magnetic properties of recording media, but that was mostly audio cassettes.

Robert

Chemistry Alchemist - 29-11-2011 at 05:15

Where would u most likly find Samarium Magnets being in use? the link below shows a picture of what 2 uses samarium has....

http://www.jce.divched.org/JCESoft/CCA/CCA4/STILLS64/S_elt/S...


ScienceSquirrel - 29-11-2011 at 05:20

Seek and ye shall find!

http://en.wikipedia.org/wiki/Samarium#Applications

http://www.ebay.co.uk/sch/i.html?_from=R40&_trksid=p5197...