Sciencemadness Discussion Board

Non-abrasive removal of 3A sieve residue ?

Sulaiman - 26-7-2020 at 02:18

I had 500g of 3A molecular sieves wet with water and ethanol in a 1000ml rbf
and I distilled off most of the ethanol using a water bath.

The flask now has residue stuck to the inner wall near the bottom of the rbf,
a rinse with conc. HCl followed by 12 hours soaking in dilute HCl removed some of the residue,
washing with detergent made no difference.

I do not want to use abrasive methods as the rbf is new and unscratched.

How can I dissolve or dislodge (presumed) aluminosilicates without damaging the rbf - any suggestions ?

unionised - 26-7-2020 at 02:37

Sodium hydroxide solution might remove the residue.
Or you might just consider this flask to have permanent, not very good, anti-bumping granules in it.

[Edited on 26-7-20 by unionised]

Sulaiman - 26-7-2020 at 03:08

I will leave hot KOH (I have no NaOH) as a last resort as it will probably eat some of the rbf along with the aluminosilicate(s).
___________________________________________________________
D'oh !
I feel dumb now ... the residue came off easily when I just used water, dtergent and a bottle brush.:P

[Edited on 26-7-2020 by Sulaiman]

draculic acid69 - 30-7-2020 at 00:06

Maybe just a room temperature soak of hydroxide rather than a hot one would be better.i wouldn't leave hydroxide as a last resort it seems to be a good option. hot hydroxide can be a last resort but it's definitely worth trying at room temperature