plante1999 - 8-2-2011 at 15:07
hi!!
i was thinking about Ti4O7 plated on ti rod
the processe i was thinking: take very pur ti rod and oxidise it in sulfuric acid electrochemicaly , take a test tube with a glass stopper with 2 hole
one hole with H2 intry and another with escaping H2O , the botom of the test tube with some tin or lead with the uncoated place of the rod will be
droped , the anode will be heated at 1000 degree c for 1 hour with H2 flow and than electrolised in brine.
thanks!
my reference is to big to be posted so i will try anoter time.
[Edited on 8-2-2011 by plante1999]
[Edited on 8-2-2011 by plante1999]
[Edited on 8-2-2011 by plante1999]
dann2 - 11-2-2011 at 15:06
What is the Anode going to be making long term?
plante1999 - 15-2-2011 at 14:32
sorry for the double post.
here the document:
<a href=http://www.filedropper.com/hayfieldpcsdevelopmentofanewmaterial-monolithicti4o7ebonexceramicrsc20010854049843><img
src=http://www.filedropper.com/download_button.png width=127 height=145 border=0/></a><br /> <div
style=font-size:9px;font-family:Arial, Helvetica, sans-serif;width:127px;font-color:#44a854;> <a href=http://www.filedropper.com >file
storage</a></div>
[Edited on 15-2-2011 by plante1999]
Zaratukhshthra - 18-2-2011 at 00:39
I doubt it could work, using Ti4O7 as anode will most probably oxidize it to (insulator) TiO2.
something like: Ti4O7 + H2O => 4TiO2 + 2H+ + 2e-
plante1999 - 18-2-2011 at 05:12
in fact this type of anode is used in manifature of chlorine (reference is up this message).
Tinamics - 8-3-2011 at 23:56
We are the producer of Ti4O7 ceramic powder. Please contact jayhuang118@126.com