There are many aspects observed then in atomic spectra that the semiclassical theory could not account for: fine structure due to relativistic
effects, effects due to spin-orbit coupling, hyperfine splitting due to the spin of the nucleus, and the electron interactions. QM is able to account
for all of these, although the last was very difficult to do accurately then because the three body problem in QM is not analytically solvable. You
separate the last as having been the only aspect the known - have you any reference to this? |