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ethanol self-condensation
Scavenging oxygen with sulfite is likely to be difficult because sulfite does not react that much mo ...
18-7-2023 at 05:54
by: clearly_not_atara
ethanol self-condensation
I believe that the first step is something to the effect of:

EtO- + O2 >> EtO3- >> HO ...
17-7-2023 at 10:02
by: clearly_not_atara
Phenol to salicaldahyde how?
The ortho-formylation of interest in drug synthesis is just one of five or six steps, depending on t ...
14-7-2023 at 05:31
by: clearly_not_atara
Preparation of Ketones by Calcium salt Pyrolysis
I've seen some claims about barium. Toady claimed that substoichiometric baryta with the mixed acids ...
14-7-2023 at 05:03
by: clearly_not_atara
Novel Ketene synthesis - First time poster, long time reader
[rquote=685712&tid=159719&author=mayko]Whether it could be a useful preparation I don't know ...
14-7-2023 at 04:07
by: clearly_not_atara
Novel Ketene synthesis - First time poster, long time reader
[quote]from what I've read[/quote]
From what I've read, the sky is green.

Where are you reading ...
13-7-2023 at 19:40
by: clearly_not_atara
Caprolactam reduction to azepane?


[file]98804[/file]
13-7-2023 at 18:23
by: clearly_not_atara
Nitroethane from ethanol
[quote]So it is possible that a working chemical artificial intelligence will appear in the not-so-d ...
12-7-2023 at 13:46
by: clearly_not_atara
Sciencemadness comment box!
[rquote=685635&tid=159717&author=Texium]I think we need a new rule on this forum of NO posti ...
12-7-2023 at 12:45
by: clearly_not_atara
Dissolving organic tissues in hydroxides
This works, but the problem is that you will probably end up spending more money on alkali than you ...
6-7-2023 at 19:44
by: clearly_not_atara
Barium peroxide from barium carbonate
Nitrate? I think that acetate might be a little simpler!
3-7-2023 at 16:17
by: clearly_not_atara
Dichloromethane ban
Truly a tragedy for everyone wanting to use an effective paint stripper.
3-7-2023 at 06:47
by: clearly_not_atara
Liquefying SO2 into a Plastic Bottle
[rquote=685314&tid=159686&author=teodor]If you can it would be great savings of money, becau ...
30-6-2023 at 21:20
by: clearly_not_atara
Sodium Bromite
This reagent turns out to be more stable than I thought. It decomposes at room temperature but it ca ...
29-6-2023 at 17:39
by: clearly_not_atara
Sciencemadness comment box!
[quote]grad school has been sucking the life out of me,[/quote]
Oh, that's quite normal. That's als ...
28-6-2023 at 17:30
by: clearly_not_atara
Sciencemadness comment box!
[rquote=685269&tid=30434&author=j_sum1]
Stickies don't do much. I think most people keep an ...
28-6-2023 at 11:37
by: clearly_not_atara
Higher oxidation states in aqueous solution
Chelate, chelate.
27-6-2023 at 17:00
by: clearly_not_atara
(HPO3)n Dehydrating agent (polyphosphoric or metaphosphoric acid)
[rquote=684974&tid=4409&author=chloric1]https://cdnsciencepub.com/doi/pdf/10.1139/v56-102

...
20-6-2023 at 13:18
by: clearly_not_atara
The capacitor arrow... Would it work?
[rquote=684737&tid=159587&author=Metallophile]Also, your capacitor arrow would discharge bet ...
10-6-2023 at 12:12
by: clearly_not_atara
Iodination of dibenazlacetone
Iodine rarely adds efficiently to electron-deficient alkenes. Simple benzyl iodides are already redu ...
8-6-2023 at 06:05
by: clearly_not_atara
Best way to dissolve bathroom mineral stains?
The challenge is not to attack the grout, too. I would usually try Soft Scrub (long-chain alkyl benz ...
2-6-2023 at 10:24
by: clearly_not_atara
Confusion on SO3 Synthesis
I'm sure it isn't easy, but I've found a couple of reports that aluminum dihydrogen phosphate dehydr ...
26-5-2023 at 14:00
by: clearly_not_atara
Acetic anhydride preparation
CaCl2 alone will not do it. See:

https://pubs.acs.org/doi/pdf/10.1021/ja01852a002
24-5-2023 at 08:27
by: clearly_not_atara
Acetic anhydride preparation
P2O5 alone was tried and failed extensively. Using calcium chloride as a cofactor is new, though.
24-5-2023 at 07:30
by: clearly_not_atara
Oxalate solubility and basic questions
You don't have to go all the way to silver. Cobalt nanoparticles can be formed from the oxalate:

...
22-5-2023 at 13:00
by: clearly_not_atara
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