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why not haloform reaction results in an α keto acid?
This is an interesting question, and I do not know the answer.

It would appear that (-)CCl3 is an ...
2-5-2011 at 13:38
by: AndersHoveland
tetraamine copper nitrate sensitivity?
As you can see in the first link, moist crystals of tetraamine copper nitrate (TACN) in a glass tube ...
2-5-2011 at 12:47
by: AndersHoveland
Explosive hazard
This was mentioned in a previous topic:
http://www.sciencemadness.org/talk/viewthread.php?tid=14278 ...
26-4-2011 at 15:39
by: AndersHoveland
Make Potassium (from versuchschemie.de)
The density of potassium metal is 0.862 g/cm3, whereas magnesium has a much higher density, 1.738 g/ ...
25-4-2011 at 10:30
by: AndersHoveland
Explosive hazard
Trichloroisocyanuric acid (TCCA) often explodes when acidified. It generally seems to be assumed tha ...
25-4-2011 at 10:20
by: AndersHoveland
hydrazine, peroxide, azide
The oxidation of hydrazine sulfate by a mixture of hydrogen peroxide and dilute sulfuric acid produc ...
25-4-2011 at 09:50
by: AndersHoveland
vicinal amino-nitroalkanes ?
Are there any instances of a stable compound with a nitro group on a carbon atom adjacent to another ...
22-4-2011 at 12:22
by: AndersHoveland
mercury methazonate
Mercury methazonate, which is a compound similar to mercury fulminate, is formed from the reaction o ...
21-4-2011 at 15:21
by: AndersHoveland
nitroalkane synthesis
It is not completely impossible to directly nitrate alkanes into nitroalkanes at room temperature, t ...
19-4-2011 at 22:48
by: AndersHoveland
Nitroethane from acetonitrile?
“The primary and secondary nitroalkanes exist in tautomeric equilibrium with an ‘aci’ or nitro ...
19-4-2011 at 12:53
by: AndersHoveland
Nitroethane from acetonitrile?
Oxidation of analine to nitrobenzene is well known.
"Peroxytrifluoroacetic Acid. II. The Oxidation ...
18-4-2011 at 13:07
by: AndersHoveland
Pepper grinder and magnesium?
Magesium metal is nearly as hard as aluminum (around Mohs 2.5).

However, magnesium-alumnium alloy ...
16-4-2011 at 14:37
by: AndersHoveland
Has anyone made sodamide?
Sodium metal and dry ammonia gas, when heated to 320-350degC, react to form sodium amide and hydroge ...
16-4-2011 at 13:14
by: AndersHoveland
permanganate and toluene reaction
A small ammount of sarcasm was involved, yes. "jamit" was asking for a balanced equation for a react ...
13-4-2011 at 14:45
by: AndersHoveland
monopropellant project
n-propyl nitrate can be prepared through nitration on n-propanol. The nitric acid used should not ha ...
13-4-2011 at 14:04
by: AndersHoveland
permanganate and toluene reaction
The reaction is probably not very clean at all, but may procede something like this:

14 C<sub& ...
13-4-2011 at 13:38
by: AndersHoveland
monopropellant project
Nitroguanidine was once used as a propellent in model rocket motors. The exhaust gases were cooler t ...
13-4-2011 at 12:42
by: AndersHoveland
Solvent for sodium amide
Is anyone aware of other solvents that can actually [i]dissolve[/i] sodium amide, without reacting w ...
13-4-2011 at 11:25
by: AndersHoveland
Ethylenedinitramine
Perhaps react acetamide with 1,2-dibromo-ethane, then after fully reacted, perform a nitration, then ...
4-4-2011 at 15:06
by: AndersHoveland
bicyclopentane
This bicyclobutane compound would be expected to have a high heat of formation caused by the added s ...
4-4-2011 at 13:59
by: AndersHoveland
Bicyclobutane with even more strain
If not for the trifluoromethyl group, could the bicyclobutane (in the strained configuration) conver ...
2-4-2011 at 06:14
by: AndersHoveland
Ethylenedinitramine
This is off topic, but I have been recently thinking about ethylene diurea (which can be prepared by ...
2-4-2011 at 03:25
by: AndersHoveland
Bicyclobutane with even more strain
Is there someone that can provide a good explanation about the shape of this molecule:

http://pub ...
1-4-2011 at 23:32
by: AndersHoveland
Ethylenedinitramine
[rquote=107894&tid=4282&author=franklyn]
I just recently had this same idea occur to me , t ...
23-3-2011 at 20:46
by: AndersHoveland
Phenol
I know this is somewhat of a different topic, but I found the following reaction to be very interest ...
22-3-2011 at 18:20
by: AndersHoveland
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