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Nitroacetone
Of course, it is possible to oxidize the CH3C(=O)CH=NOH to nitroacetone;

"...anhydrous solutions ...
25-5-2011 at 13:25
by: AndersHoveland
Nitroacetone
No, nitroacetone is not explosive. As for its toxicity, I am not sure. While 2-nitroacetic acid is v ...
25-5-2011 at 12:26
by: AndersHoveland
Tetranitromethane
Tetranitromethane has been obtained from iodopicrin I3CNO2 and silver nitrite AgNO2.
Hantzsh, Chemi ...
24-5-2011 at 13:37
by: AndersHoveland
Ammonium dinitramide
Ammonium dinitramide, with the structure NH4[+] [-]N(NO2)2, is an energetic oxidizing salt which has ...
24-5-2011 at 12:58
by: AndersHoveland
New Energetic Materials - Current Research
In Germany, Thomas Klapƶtke and Davin Piercey of the University of Munich, synthesized a double rin ...
23-5-2011 at 16:29
by: AndersHoveland
Site Backup
I think a archived backup for science madness is very important. This forum contains some of the bes ...
23-5-2011 at 15:30
by: AndersHoveland
Heat of formation of MgF2/AlF3 vs. MgO/Al2O3
Remember, the heats of formation depend not only on the energy released, but also on the [i]mass[/i] ...
23-5-2011 at 15:01
by: AndersHoveland
Chlorite and hypochlorite interactions
[rquote=210648&tid=16378&author=woelen]I'm quite sure that the reaction with formation of NO ...
23-5-2011 at 13:53
by: AndersHoveland
Chlorite and hypochlorite interactions
Woelen, after more thought, I think the reactions that may best describe your original experiment, d ...
23-5-2011 at 10:14
by: AndersHoveland
Chlorite and hypochlorite interactions
These equations may be helpful:

(8)HOCl --> (4)H2O + (2)ClO2 + (3)Cl2

(8)HClO2 --> (4)H ...
22-5-2011 at 11:45
by: AndersHoveland
Silver / Copper Nitride
[rquote=210481&tid=1855&author=AJKOER]
2 NH4OH + 2 AgNO3 --> Ag2O(a tan to black solid) ...
21-5-2011 at 14:46
by: AndersHoveland
Silver / Copper Nitride
Some pictures:

Aqueous ammonia (NH4OH) is added to silver nitrate (AgNO3). The result is a light ...
20-5-2011 at 14:49
by: AndersHoveland
A TCCA chlorination safety warning
Site about accidental industrial explosions:
http://www.chemaxx.com/explosion16a.htm

(interestin ...
18-5-2011 at 09:02
by: AndersHoveland
Azides
[rquote=210103&tid=1987&author=woelen]
If companies like Aldrich sell hydrazine in glass bo ...
18-5-2011 at 01:19
by: AndersHoveland
Expensive experiments for the amateur experimenter
Expensive experiments for the amateur experimenter?

Can we include expected medical receipts for ...
17-5-2011 at 21:47
by: AndersHoveland
Alternative to Nitric acid /research
That label is amusing: "Ca(OCl)2 [b]+ impurities[/b] ".

Just what exactly [i]are[/i] those pesky ...
17-5-2011 at 21:37
by: AndersHoveland
Triple Salt Frees halogens with ease!
You [i][b]are[/b][/i] aware that there are several other ways of oxidizing halides to their respecti ...
17-5-2011 at 21:22
by: AndersHoveland
Stabilization of organic peroxides
Actually, one would think that acidity, in one way, may help to chemically stabilize organic peroxid ...
17-5-2011 at 16:07
by: AndersHoveland
Alternative to Nitric acid /research
The reaction which was meant is:
Ag + Fe[+3] + Cl[-] --> AgCl + Fe[+2]

Of course ferric nit ...
17-5-2011 at 13:51
by: AndersHoveland
decomposition hypochlorous acid
[rquote=209951&tid=16330&author=m1tanker78]I exclusively use 3% H2O2 + concentrated HCl to e ...
17-5-2011 at 13:37
by: AndersHoveland
rxn of P4 with Na in benzene
[rquote=209885&tid=16312&author=woelen]But after the reaction there indeed is phosphide. The ...
16-5-2011 at 13:23
by: AndersHoveland
Alternative to Nitric acid /research
I have noticed that 30% concentrated H2O2 with 30% concentrated HCl solution is able to rapidly atta ...
16-5-2011 at 13:14
by: AndersHoveland
Stabilization of organic peroxides
Acetone peroxide [b]is[/b] dangerous!

Because it is easy to make, acetone peroxide is popular amo ...
14-5-2011 at 12:48
by: AndersHoveland
Transition metal permanganates/manganates.
[rquote=209337&tid=16276&author=woelen]But if you have to start from KClO4 then you are not ...
11-5-2011 at 15:00
by: AndersHoveland
preparation or proplene carbonate from plastic
Propylene carbonate is potentially very interesting as a solvent for Finkelstein reactions, since it ...
11-5-2011 at 14:36
by: AndersHoveland
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