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Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]To form it from Mg(OiPr)2 while producing CO32-, you would end up with a (MgiPr)+ moiety. Par ... |
18-11-2013 at 23:33
by: deltaH |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
Thanks for splitting this off, shame we were really cluttering up that thread, sorry, but this topic ... |
18-11-2013 at 13:02
by: deltaH |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]I've used ethylene carbonate for alkylation before, so yes, it does work. However, magnesium ... |
18-11-2013 at 11:30
by: deltaH |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
I hear you, but alkyl carbonates are also alkylating agents... granted weak ones, but nevertheless. ... |
18-11-2013 at 08:14
by: deltaH |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]Where does the hydride come from? You have just magnesium metal. This could react with iPrOH ... |
18-11-2013 at 03:07
by: deltaH |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[rquote=307615&tid=27324&author=vulture]UC:
Isopropylchloride is added, reaction starts, ... |
18-11-2013 at 01:43
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
[rquote=307612&tid=27270&author=vulture]1) Do we have any references for this attack of amin ... |
18-11-2013 at 01:07
by: deltaH |
Speculative reaction of alcohols to carbonic acids with Mg and CO2
[quote]@deltaH: magnesium reacts with alcohols to give the alcoxide, i.e., it reduces the hydroxyl h ... |
17-11-2013 at 21:56
by: deltaH |
grignard reaction
[quote]If you knew anything about the mechanism of a grignard reaction, you would know that this is ... |
17-11-2013 at 17:07
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
Amines tend to readily attach to the ring position of quinones under basic conditions, accompanied b ... |
17-11-2013 at 16:36
by: deltaH |
grignard reaction
? 2iPrOH(l) + 3Mg(s) + 4CO[sub]2[/sub](s) => Mg(iBuO[sub]2[/sub])[sub]2[/sub](s) + 2MgCO[sub]3[/s ... |
17-11-2013 at 15:29
by: deltaH |
Hydrogenated of mesityl oxide with acetic acid
If you find that carbon anodes have insufficient durability for your water electrolysis needs, consi ... |
17-11-2013 at 14:51
by: deltaH |
Hydrogenated of mesityl oxide with acetic acid
Hold on, I'm still confused here...
[quote]HgCl2 and Al will probably reduce to alkane like metal ... |
17-11-2013 at 13:19
by: deltaH |
Hydrogenated of mesityl oxide with acetic acid
[b]plante1999[/b], would the use of Al in this case not result in poor selectivity by way of reducti ... |
17-11-2013 at 11:51
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
Probably DABCO, but that is speculation! Incidentally, DABCO is one of a few simple amines that has ... |
16-11-2013 at 14:00
by: deltaH |
Oxydising iodides
Oxone (persulfuric acid salt) quickly produces the free halogen from salt solution. I once had the m ... |
16-11-2013 at 05:38
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
[quote]So, just to be clear, DABCO or Triethylamine will work as a base catalyst, remove the unwante ... |
16-11-2013 at 01:50
by: deltaH |
General Discussion of Terbium Compounds
[quote]However, I'm pretty sure I'll be doing this in methanol or ethanol - it sounds a whole lot si ... |
15-11-2013 at 15:41
by: deltaH |
Electrolyzing NaOH: finally succeeded !
[b]metalresearcher[/b], a silver plated spoon or one marked EPNS might make a good anode. Silver oxi ... |
15-11-2013 at 14:58
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
DABCO should do a marvelous job of elimination the bromines for you, but then you will need it in st ... |
15-11-2013 at 11:04
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
Now it makes more sense, thanks for the info.
Okay, a good base catalyst for this from my experie ... |
15-11-2013 at 00:38
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
It would really help if you could give a bit more info [b]APO[/b], what are you after, a base cataly ... |
14-11-2013 at 11:29
by: deltaH |
2,5-Dibromo-1,4-benzoquinone Reactivity?
I have myself reacted chloranal with sodium methoxide in methanol (refluxed). I will try to recall s ... |
14-11-2013 at 05:54
by: deltaH |
whistle mix problems
What you are doing is very dangerous and illegal without a license. Be warned!
To show you just h ... |
14-11-2013 at 02:07
by: deltaH |
Hafnium - Plasma Torch Electrode
I was thinking of Niobium and that lead me to the niobium containing alloy Inconel 718 and that lead ... |
13-11-2013 at 01:29
by: deltaH |
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