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Purifying Denatured absolute EtOH Superheating problem
I do not understand why you are trying to "purify" absolute alcohol. You can't make it potable and t ...
25-10-2008 at 08:14
by: Sauron
CCl3Br -> CCl4 or CHCl3
In my sketch above, 10 is the Michael addition product of enamine 5 (methyl 3-aminocrotonate, formed ...
24-10-2008 at 21:54
by: Sauron
sourceachem (UK)
Atropine, huh?

Suggest anything to anyone but me?
24-10-2008 at 17:19
by: Sauron
CCl3Br -> CCl4 or CHCl3
The Katritzky paper posted above concludes from NMR experimental evidence that the main pathway of t ...
24-10-2008 at 17:08
by: Sauron
specific chemical requests
Nicodem has a good point.

Rarely indeed do I come up empty handed from a really serious effort at ...
24-10-2008 at 07:53
by: Sauron
CCl3Br -> CCl4 or CHCl3
I guess I ought to have a closer look at the Knoevenagel reaction, and reread the Katritzky paper on ...
23-10-2008 at 21:05
by: Sauron
"Who-me?"
During WWII The technical-services department of the Office of Strategic Services (OSS) created a su ...
23-10-2008 at 18:52
by: Sauron
specific chemical requests
A preparative assistance only forum? I assume the same principles would apply as are already in pla ...
23-10-2008 at 12:49
by: Sauron
CCl3Br -> CCl4 or CHCl3
And here is the Paul Rabe paper from Ann. in 1904.

The original Knoevenagel prep paper from 1894 ...
23-10-2008 at 10:42
by: Sauron
CCl3Br -> CCl4 or CHCl3
Here are the pages from the ACS monograph on Formaldehyde (forum library.)

As you will see, Knoev ...
23-10-2008 at 09:30
by: Sauron
CCl3Br -> CCl4 or CHCl3
Thanks. I think it will be very practical.

Regarding the Hantzsch, I had a look at the ACS monogr ...
23-10-2008 at 08:39
by: Sauron
org syn website -> malware
A pity that Google is being such a nanny-ninny.

Can you access orgsyn.org via Yahoo's SE? Or some ...
22-10-2008 at 20:50
by: Sauron
CCl3Br -> CCl4 or CHCl3
I am looking at various Hantzsch intermediates.

-- Ethyl 3-aminocrotonate - prepared by bubbling ...
22-10-2008 at 19:39
by: Sauron
The short questions thread (1)
I have not looked in Beilstein because (1) I have no online access and (2) the reference is to the s ...
22-10-2008 at 19:07
by: Sauron
org syn website -> malware
Complain to Google.
22-10-2008 at 18:10
by: Sauron
The short questions thread (1)
Hopefully this is a short question. I am frustrated trying to find lit. on the preparation of ethyl ...
22-10-2008 at 08:15
by: Sauron
org syn website -> malware
The Org Syn site now appears to be operating normally. I just ran a search and got no AV warning fro ...
21-10-2008 at 23:38
by: Sauron
org syn website -> malware
The Org Syn site passed a hijacker to this computer called JD/downloader and another called IEexploi ...
21-10-2008 at 22:27
by: Sauron
CCl3Br -> CCl4 or CHCl3
If the photolytic bromination of the arene can be driven to completion or nearly so then we are left ...
21-10-2008 at 19:51
by: Sauron
CBrCl3 + Toluene -> Benzyl Bromide + CHCl3 !
We have a whole new ballgame:

It turns out that bromotrichloromethane is a brominating reagent.
...
21-10-2008 at 08:24
by: Sauron
CCl3Br -> CCl4 or CHCl3
The way the mechanism of the Hantzsch Dihydropyridine Synthesis is almost always represented is that ...
20-10-2008 at 21:00
by: Sauron
Eugenol
MDL ISIS, then Export as jpg. That actually generates a wmf. Then Photoshop to reduce the image size ...
20-10-2008 at 15:01
by: Sauron
Fluoromethanes and fluoro-halomethanes
Give me a little time to dig out my papers on this topic and I will do my best to help.
20-10-2008 at 02:28
by: Sauron
CCl3Br -> CCl4 or CHCl3
Not a terribly productive day so far.

The 82 page Hantzzsch paper turned out to concern dihydroco ...
20-10-2008 at 02:26
by: Sauron
CCl3Br -> CCl4 or CHCl3
Klute:

I am awaiting the seminal 82-pqge paper by Aurthus Hantzsch.

The later paper by him inv ...
19-10-2008 at 18:49
by: Sauron
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