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Sodium hydroxide is a good drying agent for pyridine.
11-5-2021 at 17:52
by: DraconicAcid
Aldehyde oxidation
Why would you add the acid to the bleach first, instead of the aldehyde? If you acidify the bleach ...
11-5-2021 at 12:01
by: DraconicAcid
Aldehyde oxidation
[rquote=659769&tid=157419&author=zed]
Is Sodium Perborate in Acetic Acid, not suitable for ...
11-5-2021 at 11:50
by: DraconicAcid
Perfluorpolyeter
I very seriously doubt it.
11-5-2021 at 11:50
by: DraconicAcid
Aldehyde oxidation
[rquote=659741&tid=157419&author=Pinnick][rquote=659734&tid=157419&author=AvBaeyer]T ...
11-5-2021 at 08:10
by: DraconicAcid
CsICl4 caesium tetrachloroiodate
My mistake, I've got tetramethylammonium, not tetraethyl.

I did get a nice little vial full of te ...
10-5-2021 at 22:54
by: DraconicAcid
Aldehyde oxidation
I suspect otherwise, but I've never tried it. Isopropanol will stand up to chlorite (which is a wea ...
10-5-2021 at 11:02
by: DraconicAcid
Aldehyde oxidation
No. Hypochlorite will oxidize secondary alcohols to ketones. Acetone might be worth a try.
10-5-2021 at 10:32
by: DraconicAcid
Separating cloudy suspension of Benzyl Alcohol on water
I think dioxane is miscible with water, isn't it? Just like THF?

If you had something like aniso ...
10-5-2021 at 09:40
by: DraconicAcid
Synthesis of Hexahydrocannabinol
[rquote=659563&tid=157403&author=stoichiometric_steve]Efficient one-pot synthetic approaches ...
7-5-2021 at 09:04
by: DraconicAcid
methanol/ionic liquid electroplaing of metals
[quote]I lookued up organometallic. Are you objecting because the oxygen an oxygen likely present? ...
6-5-2021 at 20:15
by: DraconicAcid
methanol/ionic liquid electroplaing of metals
If you mean ethyl acetate, say ethyl acetate, not "ethanol-acetate ester". The iron may plate out o ...
5-5-2021 at 17:32
by: DraconicAcid
Copper complexes with tris
I honestly don't remember the exact details, but depending on pH, you can have singly- or doubly- de ...
5-5-2021 at 17:18
by: DraconicAcid
Copper complexes with tris
It doesn't surprise me that the hydroxyl can be deprotonated when chelating a copper(II) ion- appare ...
5-5-2021 at 11:09
by: DraconicAcid
The Short Questions Thread (4)
I don't think so, but that's a good example.
4-5-2021 at 16:14
by: DraconicAcid
What is this metal?
Zinc can be passivated and not react with acid in the absence of copper.
4-5-2021 at 14:40
by: DraconicAcid
Nomenclature of Coordinative Compounds
Ti(Cp)2Cl2 or Cp2TiCl2. (Cp)2[TiCl2] would suggest that the cyclopentadienyls are cations, and not ...
4-5-2021 at 08:41
by: DraconicAcid
methanol/ionic liquid electroplaing of metals
[rquote=659304&tid=157386&author=semiconductive]I'm just thinking acetate and acetate ... ar ...
3-5-2021 at 08:07
by: DraconicAcid
Synthesis of Ethyl Methylphenylglycidate
Work with the simple and safe stuff before trying to work with the chlorinated stuff. Try a selecti ...
30-4-2021 at 20:50
by: DraconicAcid
What chemistry are you working on.
I have some amides I'm planning to make, so the students can have them as unknowns in September. I ...
30-4-2021 at 10:19
by: DraconicAcid
Capsasin Hydrolysis
Amides are a pain in the expletive to hydrolyze. The only time I've successfully hydrolyzed piperin ...
28-4-2021 at 08:13
by: DraconicAcid
Dissolving nonmetals in ionic liquids
Might be worth a try. You might find that the solubility is very different, due to the protic natur ...
28-4-2021 at 04:03
by: DraconicAcid
My Introduction
I personally wouldn't go anywhere near Russia until Putin is deep in his grave, but welcome to the f ...
27-4-2021 at 19:20
by: DraconicAcid
Isolation of 1,1-diphenyl ethanol
I suspect that the intent was to dissolve the product in ether, add hexane, let the ether evaporate ...
27-4-2021 at 13:32
by: DraconicAcid
Isolation of 1,1-diphenyl ethanol
Are you sure your product will even be soluble in hexane? I'd expect it to be more soluble in aceto ...
27-4-2021 at 13:21
by: DraconicAcid
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