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DDNP & related compounds: The über thread!
There is still another third isomer of DDNP that is less stable than o-DDNP. so it could be that o-D ...
23-5-2015 at 04:00
by: Rosco Bodine
DDNP & related compounds: The über thread!
Yes there would seem to be a composite similar to ASA which uses p-DDNP as the bulk component instea ...
22-5-2015 at 19:12
by: Rosco Bodine
DDNP & related compounds: The über thread!
There were concerns about the stability of the o-DDNP when mixed or in contact with azide or other u ...
22-5-2015 at 17:41
by: Rosco Bodine
DDNP & related compounds: The über thread!
Confinement has benefit and the snap of 5 mg sample shows that. But it appears the literature report ...
22-5-2015 at 16:56
by: Rosco Bodine
DDNP & related compounds: The über thread!
I am not convinced there is not some yet to be revealed difference based on the earlier side by side ...
22-5-2015 at 12:19
by: Rosco Bodine
DDNP & related compounds: The über thread!
Yeah the "low actinic" glassware and the brown or amber glass have been around for a long time for a ...
22-5-2015 at 06:54
by: Rosco Bodine
DDNP & related compounds: The über thread!
Yeah but just because d 1.5 HNO3 is specified doesn't mean it wasn't white that they used :D RFNA i ...
22-5-2015 at 05:29
by: Rosco Bodine
DDNP & related compounds: The über thread!
I am not one to criticize success. What works for you works for me.

Sorry I missed that before a ...
22-5-2015 at 03:53
by: Rosco Bodine
DDNP & related compounds: The über thread!
This reference would provide a good strategy for purification.

http://pubs.acs.org/doi/abs/10.102 ...
21-5-2015 at 19:09
by: Rosco Bodine
DDNP & related compounds: The über thread!
Your old witness plate looks like a typical witness protection program success story :D You can sto ...
20-5-2015 at 14:10
by: Rosco Bodine
DDNP & related compounds: The über thread!
Amalgamated aluminum dropped into a xylene solution of sulfur might produce Aluminum Sulfide which n ...
20-5-2015 at 10:19
by: Rosco Bodine
DDNP & related compounds: The über thread!
There are alternatives to H2S generation which do not involve thermal cracking of hydrocarbons. Sim ...
20-5-2015 at 08:50
by: Rosco Bodine
DDNP & related compounds: The über thread!
I understand. My earlier post was edited, but I am leaving the description for the isomers for possi ...
20-5-2015 at 06:48
by: Rosco Bodine
DDNP & related compounds: The über thread!
[rquote=405631&tid=439&author=Hennig Brand]

You are right, it may just take a little more ...
20-5-2015 at 05:44
by: Rosco Bodine
DDNP & related compounds: The über thread!
The ammonium salt of the acetylisopicramic acid has low solubility in cold water and good solubilit ...
19-5-2015 at 17:55
by: Rosco Bodine
DDNP & related compounds: The über thread!
Please share the patents you are seeing report this.

It may be the holding time was too short f ...
19-5-2015 at 16:56
by: Rosco Bodine
DDNP & related compounds: The über thread!
Hmmm.....this is looking promising. The iso-DDNP seems to have more pop. Probably has a lower critic ...
19-5-2015 at 16:30
by: Rosco Bodine
DDNP & related compounds: The über thread!
The acetylated isopicramic acid obtained directly from nitration of the paracetamol could very possi ...
19-5-2015 at 06:13
by: Rosco Bodine
DDNP & related compounds: The über thread!
Yes pictures are good and keep careful notes.

Here's some insight into the chemistry involved.

...
18-5-2015 at 18:11
by: Rosco Bodine
DDNP & related compounds: The über thread!
The picramic acid salts and isopicramic acid salts are both indicator dyes for pH, with the fading o ...
18-5-2015 at 14:41
by: Rosco Bodine
DDNP & related compounds: The über thread!
Yes that is the article, thank you. I deleted the reference request.

Notice toward the end of t ...
18-5-2015 at 14:00
by: Rosco Bodine
DDNP & related compounds: The über thread!
Neutralization of the spent nitration mixture (may) not be required. GB24409 describes the product ...
18-5-2015 at 13:32
by: Rosco Bodine
dinitrobenzofuroxan derivatives
The nitration conditions of US3641154 are applicable.

It was GB24409 that described a nitration ...
17-5-2015 at 23:26
by: Rosco Bodine
DDNP & related compounds: The über thread!
@nitro-genes

There is a nexus between this thread and another thread where you reported nitration ...
17-5-2015 at 10:15
by: Rosco Bodine
help make white fuming nitric acid.
It is possible to break the azeotrope by adding to the aqueous HNO3 a nitrate salt which is hygrosco ...
17-5-2015 at 08:03
by: Rosco Bodine
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