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Organic Hypochlorites
Some comments on alkyl hypochlorites from Sandmeyer:

Speaking of EtClO, [i]Very surprising is the ...
27-6-2009 at 18:24
by: Formatik
Nitric Acid Synthesis
I haven't worked on it since, it was really just a probe to see if ammonia oxidation is even success ...
25-6-2009 at 09:00
by: Formatik
Chloroacetone tear gas: A Theory, A Mishap, and Questions
[rquote=155402&tid=11282&author=-TheMadMen-]Thanks Formatik, the only problem is, chloroacet ...
18-6-2009 at 22:48
by: Formatik
Synthesis of 3-Nitrophthalic Acid; Luminol Precursor
Some more references on 3-nitrophthalic acid:

Formation: by heating 4-hour heating of 1g 3-nitro- ...
18-6-2009 at 09:45
by: Formatik
Storage of Fuming Nitric acid
If you store the fuming HNO3 in a glass bottle with a glass stopper, then you shouldn't have to worr ...
14-6-2009 at 15:29
by: Formatik
Nitric Acid Synthesis
[rquote=154978&tid=2176&author=cobrasniper555] I’m sure there’s many flaws in this desig ...
14-6-2009 at 15:25
by: Formatik
Nitric Acid Synthesis
[rquote=154923&tid=2176&author=cobrasniper555]@Formatik: Very cool! I have been doing resear ...
13-6-2009 at 12:10
by: Formatik
Best and worst smelling chemicals?
I dunno, haven't seen it described elsewhere. Just don't lead H2S into acetone and conc. HCl and try ...
12-6-2009 at 16:06
by: Formatik
Best and worst smelling chemicals?
In the paper, they state: [i]according to our perceptions, the intensity of the odor of this substan ...
12-6-2009 at 12:03
by: Formatik
Chloroacetone tear gas: A Theory, A Mishap, and Questions
I've read some of the old literature which state HCl is formed in the Cl2-chlorination. This apparen ...
12-6-2009 at 11:53
by: Formatik
Silanes, self-igniting gases
Then again, the German wiki for silanes ("Silane") states Wöhler observed from his "silicon-contain ...
10-6-2009 at 08:44
by: Formatik
HCl Preparation with no other strong acid
If you're after HCl, how about using no acidic compounds at all to form it? If you take some hydrate ...
7-6-2009 at 12:22
by: Formatik
Preparation of cyanides
[rquote=154265&tid=23&author=KnooBill]First post here, hello. I read all 10 pages of it, and ...
6-6-2009 at 19:12
by: Formatik
Best and worst smelling chemicals?
Well at first I didn't know what to look for with chlorine dioxide, but after reading some reference ...
5-6-2009 at 14:57
by: Formatik
Best and worst smelling chemicals?
The horrible stench of asparagus pee is from a variety of sulfurous compounds, some of which are men ...
5-6-2009 at 12:47
by: Formatik
Best and worst smelling chemicals?
The worst smelling set of chemicals I've ever smelled occurred after ingesting a concentrated soup o ...
5-6-2009 at 10:07
by: Formatik
HCl Preparation with no other strong acid
Nitric acid indeed can't be obtained that way. Since as stated, alkali nitrate and hydrochloric acid ...
3-6-2009 at 09:38
by: Formatik
chemiluminescence!!
Here's some compounds that produce chemiluminescence 1 to 1.4 times more intensely than luminol: htt ...
1-6-2009 at 22:50
by: Formatik
Primordial chemicals
Black poplar (Populus nigra L.) leaves contain salicin. Willow tree bark is rich in salicin. Wood so ...
1-6-2009 at 22:42
by: Formatik
CS2 a Different Way
[i]Since the work of Levi [1] concerning dithioformates, these salts have been only briefly mentione ...
31-5-2009 at 15:36
by: Formatik
Hydrogen peroxide synthesis - 2-ethyl-9,10-dihydroxyanthracene
Look especially in the patent literature. E.g. see example 3 of the attached patent below.

[file ...
31-5-2009 at 14:46
by: Formatik
Silanes, self-igniting gases
After a bit of digging, from Lehrbuch der anorganischen Chemie by Holleman,etc. I've found out that ...
27-5-2009 at 11:19
by: Formatik
Chlorate from pool chem?
The pink is the hypochlorite in aq. form (the same way NaClO takes on a yellow color). Hg from a the ...
26-5-2009 at 19:19
by: Formatik
Primordial chemicals
What all can be done with NaCl?

NaCl when glowed with boric acid and air is let in at the same ti ...
24-5-2009 at 17:16
by: Formatik
Controlled Bacterial Nitrification (salpeter production, using nitrosomonas etc)
[rquote=140089&tid=11388&author=Formatik] About 3 hours heating [at 400 deg.] of KCNO in a w ...
24-5-2009 at 12:59
by: Formatik
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