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Catboy Chemical Society
You have manganese and copper chlorides on your face!
30-11-2022 at 17:37
by: clearly_not_atara
Thermal dehydration of amides to nitriles catalyzed by vanadium on hydrotalcite
Among methods for amide dehydration, this is particularly convenient: heterogeneous catalyst, purely ...
30-11-2022 at 16:36
by: clearly_not_atara
Catboy Chemical Society
Lmao. You're really leaning into the drama I see. Don't let me see you working without PPE even as a ...
30-11-2022 at 08:51
by: clearly_not_atara
Bromination of 1,3 benzodioxole to 5-Bromo-1,3-benzodioxole?
Pumukli: There is a footnote signifier by the entry, but the footnote is obviously wrong, because it ...
29-11-2022 at 05:21
by: clearly_not_atara
Bromination of 1,3 benzodioxole to 5-Bromo-1,3-benzodioxole?
Table 2, entry 8.
27-11-2022 at 21:01
by: clearly_not_atara
NH3 Extraction from Mixed Gases
I think you would probably prefer magnesium sulfate (Epsom salt) for sequestering ammonia, since CaS ...
26-11-2022 at 18:20
by: clearly_not_atara
Synthesis of gemstone-chromium doped gallium oxide,color-change at UV
This paper indicates a high hardness for Ga2O3 which is indeed comparable to alumina:

https://par ...
26-11-2022 at 18:19
by: clearly_not_atara
A foray into phenethylamines of the Shulgin kind
For the acylation of p-dimethoxybenzene, I think you could probably use Ac2O with a Brønsted acid c ...
26-11-2022 at 15:01
by: clearly_not_atara
AlCl3 by double displacement?
If you can buy zinc chloride, why not buy aluminum chloride? I guess you could do the reaction for t ...
21-11-2022 at 18:34
by: clearly_not_atara
de-aromatization and removal of ethene bonds.
Generally de-aromatization reductions are most feasibly achieved with the Birch-type systems. Birch ...
20-11-2022 at 17:29
by: clearly_not_atara
AlCl3 by double displacement?
The reaction is endothermic. Oxidation of MnCl2 by atmospheric oxygen might drive the result in some ...
20-11-2022 at 08:25
by: clearly_not_atara
Formic Acid Dehydration
[rquote=678697&tid=159088&author=Texium]In the past, I’ve dehydrated oxalic acid by azeotr ...
19-11-2022 at 20:28
by: clearly_not_atara
AlCl3 by double displacement?
[rquote=678692&tid=159094&author=blogfast25]
There are other chlorides that would work: CuC ...
19-11-2022 at 20:08
by: clearly_not_atara
Formic Acid Dehydration
According to a paper found by Klute, formic acid can be dehydrated over anhydrous oxalic acid:

ht ...
19-11-2022 at 10:05
by: clearly_not_atara
AlCl3 by double displacement?
Every time this discussion comes up I point out that MnCl2 can be dried by heating and should react ...
19-11-2022 at 09:59
by: clearly_not_atara
Preparation of STABLE colloidal gold
Most emulsions need surfactants to stabilize them.
17-11-2022 at 21:21
by: clearly_not_atara
Preparation of ionic nitrites
You could see a reaction like

4 NO + 2 OH- >> N2O + 2 NO2- + H2O

As to whether this act ...
17-11-2022 at 21:17
by: clearly_not_atara
ZnCl2 * nH2O, purificiation
[rquote=677588&tid=158980&author=teodor]
But it is no possible to get ZnCl2 by evaporating ...
16-11-2022 at 16:00
by: clearly_not_atara
Chloride to perchlorate without errosion.
Chloride might actually be reducing PbO2:

4 Cl- + PbO2 >> PbCl2 + 2 ClO- + 2 e-
6-11-2022 at 09:01
by: clearly_not_atara
Fastest way to make Iron (III) chloride without peroxide?
If you just start with iron (III) oxide and dissolve it in HCl, the product should be FeCl3. So you ...
5-11-2022 at 06:38
by: clearly_not_atara
Reflections on the vanadium-chlorine water-splitting process
[quote]Then Cl2 reacts with water at 100C to release O2 and produce HCl. (I have not heard of this r ...
2-11-2022 at 16:55
by: clearly_not_atara
Reflections on the vanadium-chlorine water-splitting process
A number of papers have come out describing a vanadium-chlorine thermochemical water-splitting cycle ...
2-11-2022 at 14:54
by: clearly_not_atara
Does triiodoethanol exist?
Chloral is not further oxidized by chlorine, which is why it is so easy to make. Only when alkali is ...
1-11-2022 at 19:02
by: clearly_not_atara
Cleaning chromium(III) oxide stains from a flat bottom flask
Could try forming the oxalate complex with refluxing potassium hydrogen oxalate?
29-10-2022 at 10:20
by: clearly_not_atara
Preparation of ionic nitrites
Adding NiCl2 to a solution containing KNO2 and KNO3 should precipitate K4Ni(NO2)6*H2O selectively as ...
28-10-2022 at 20:06
by: clearly_not_atara
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