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Happy Holidays
This just in from Cambridge …..enjoy and Merry Christmas

https://www.youtube.com/watch?v=5-7jnu ...
24-12-2015 at 12:44
by: Rosco Bodine
Happy Holidays
Merry Christmas to all

https://www.youtube.com/watch?v=nclEIKiBNls

<iframe width="640" hei ...
24-12-2015 at 10:16
by: Rosco Bodine
SpaceX - Falcon 9 Soft Landing Return First Stage Success
Those niobium alloy nozzles are not cheap, so it makes sense they would want them back, and getting ...
22-12-2015 at 15:50
by: Rosco Bodine
SpaceX - Falcon 9 Soft Landing Return First Stage Success
https://www.youtube.com/watch?v=IkqleoBZq_4

<iframe width="640" height="360" src="https://www. ...
22-12-2015 at 10:56
by: Rosco Bodine
DDNP & related compounds: The über thread!
I was thinking about the disputed "rearranged" 6 diazo of DDNR from the earlier Klapotke article rei ...
7-12-2015 at 17:52
by: Rosco Bodine
DDNP & related compounds: The über thread!
There is a conspicuous absence of original references and history regarding the DDNR and an odd avoi ...
7-12-2015 at 11:52
by: Rosco Bodine
DDNP & related compounds: The über thread!
That is interesting and it also appears to be a slow reaction so it could form good crystals. Should ...
31-10-2015 at 09:34
by: Rosco Bodine
DDNP & related compounds: The über thread!
http://www.sciencemadness.org/talk/viewthread.php?tid=8815

This looks interesting that the DNSA c ...
30-10-2015 at 18:37
by: Rosco Bodine
DDNP & related compounds: The über thread!
There is likely a specific concentration for the HNO3 solution of isopicramic acid useful for the di ...
6-10-2015 at 14:18
by: Rosco Bodine
DDNP & related compounds: The über thread!
What would work best for a crystal modifier scheme is total guesswork so it is a shot in the dark to ...
30-9-2015 at 07:56
by: Rosco Bodine
crystallization modifiers
There was earlier in this discussion a speculation that there may be a modified crystal formation po ...
28-9-2015 at 11:51
by: Rosco Bodine
textbook download links
Here are a couple of textbook download links that are for books provding some general information
...
28-9-2015 at 10:30
by: Rosco Bodine
DDNP & related compounds: The über thread!
I was actually curious about some of these process details in reviewing the pre-publication writeup, ...
26-9-2015 at 21:36
by: Rosco Bodine
DDNP & related compounds: The über thread!
Did you try what I suggested about the order of addition, dissolving the isopicramic acid in the aci ...
26-9-2015 at 13:51
by: Rosco Bodine
guanazole reaction revisited
From about 7 years ago to again about 4 years ago and later a couple of years ago the subject of gua ...
24-9-2015 at 14:45
by: Rosco Bodine
DDNP & related compounds: The über thread!
@ nitro-genes When you first described the use of copper for the diazotization it was done first for ...
23-9-2015 at 20:16
by: Rosco Bodine
DDNP & related compounds: The über thread!
Trying to offer an off the top of my head, what I think could work kind of guess, without doing the ...
18-9-2015 at 08:23
by: Rosco Bodine
DDNP & related compounds: The über thread!
I wonder what using the copper in a mixture of nitric and acetic acid might produce. Any residual a ...
17-9-2015 at 15:06
by: Rosco Bodine
DDNP & related compounds: The über thread!
Acetone recrystallization may work or mixed solvent recrystallization may work, but generally it is ...
17-9-2015 at 09:19
by: Rosco Bodine
DDNP & related compounds: The über thread!
@ greenlight Yes the experimental for the use of copper particularly is uncharted territory and is ...
17-9-2015 at 07:20
by: Rosco Bodine
DDNP & related compounds: The über thread!
The diazotization using the copper and a nitric acid solution, or mixed acid solution of the isopicr ...
16-9-2015 at 21:12
by: Rosco Bodine
DDNP & related compounds: The über thread!
It was mainly the heating of the isopicramic acid with fuming HNO3 that would possibly be a safety i ...
16-9-2015 at 10:34
by: Rosco Bodine
DDNP & related compounds: The über thread!
WRT "Sprengel composition" that was my observation regarding a real safety concern which does arise ...
16-9-2015 at 09:14
by: Rosco Bodine
5-diazo-styphnic acid ....(exist?)
On the preceding page the 3-diazo-picric acid was documented

http://www.sciencemadness.org/talk/v ...
14-9-2015 at 15:12
by: Rosco Bodine
DDNP & related compounds: The über thread!
It is my guess you have likely gotten a lot of the DNAc in high yield and not much else. I think yo ...
11-9-2015 at 14:23
by: Rosco Bodine
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