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Storing Diethylamine?
Here is some information on purification from Armarego:

[b]Diethylamine[/b] [109-89-71 M 73.1, b ...
15-9-2009 at 13:04
by: sonogashira
The short questions thread (2)
There is a reference to "a-Methyl- 3,4-methylenedioxyphenylpropionamide" in this paper starting at t ...
8-9-2009 at 11:31
by: sonogashira
mechanisms of calcium carbide reactivity
I spent a (thankfully!) small time working in a foundry when I was young.

I recall they used calc ...
8-9-2009 at 11:17
by: sonogashira
deacetylation, please help?
It is a very easy transformation using acid or base hydrolysis - Take your pick.:)

Best luck!;)
...
8-8-2009 at 00:25
by: sonogashira
cyclic diester
High dilution with ethylene glycol will make cyclization more probable, but i do not know if the yie ...
4-8-2009 at 08:08
by: sonogashira
The short questions thread (2)
Thank you for that information also Tim, i did not know that lead salts could be used too.

I hav ...
3-8-2009 at 08:22
by: sonogashira
The short questions thread (2)
Thanks, i'll try that. I just thought that perhaps silver acetate in dilute acetic acid could be use ...
2-8-2009 at 12:17
by: sonogashira
The short questions thread (2)
But maybe with a large excess it will push the equilibrium in the correct direction- do you think?
...
2-8-2009 at 11:47
by: sonogashira
The short questions thread (2)
Hi, I have a possibly very silly question but i will ask anyway - with slight shame: :)

[u]Is it ...
2-8-2009 at 10:28
by: sonogashira
Oxidation of Methyl Tiglate
Here is better paper than mechanism crap I posted before! :)

Peracetic acid as oxidant and decent ...
18-7-2009 at 08:27
by: sonogashira
Oxidation of Methyl Tiglate
Here is a tetrahedron review of epoxidation mechanism.

Methyl Methacrylate epoxidation is covered ...
17-7-2009 at 13:24
by: sonogashira
Nitrobenzene
[rquote=157872&tid=12532&author=itchyfruit]So it would seem,but my book (chemistry for dummi ...
17-7-2009 at 04:55
by: sonogashira
otc sodium borohyride
[rquote=153982&tid=12284&author=DJF90]The -I effect (inductively withdrawing) of the -OMe gr ...
31-5-2009 at 14:09
by: sonogashira
Dreams
I once took 5-htp supplement before bed (as instructed!) and was up all night with the most vivid dr ...
12-3-2009 at 19:59
by: sonogashira
Synthesis of p-nitrobenzoic acid
I know of some oxidations of PABA with oxone in very good yields (in-situ DMDO formation) but it see ...
13-2-2009 at 08:52
by: sonogashira
The short questions thread (1)
^ Carboxylic acid will be formed. Phenylacetic acid.
12-2-2009 at 17:12
by: sonogashira
The short questions thread (1)
And here is another very interesting paper for you Mr Picric Acid.

I go back to Taiwan in the new ...
29-12-2008 at 07:08
by: sonogashira
The short questions thread (1)
[quote][i]Originally posted by Picric-A[/i]My aim is 4-nitrobenzoic acid by the way :)[/quote]

He ...
29-12-2008 at 06:50
by: sonogashira
The short questions thread (1)
The merck index gives [url=http://v3.espacenet.com/searchResults;jsessionid=0E6AE854E711C102FA8872FF ...
5-12-2008 at 14:34
by: sonogashira
Aesthetic crystal structures? Please post here!
Nice! I'll have to do some experimenting with these I think..... I've now got some bismuth powder on ...
29-10-2008 at 15:02
by: sonogashira
Aesthetic crystal structures? Please post here!
Thanks!! :) Some really nice crystals there.. Bismuth's still my favorite though :P

I might have ...
29-10-2008 at 08:36
by: sonogashira
Aesthetic crystal structures? Please post here!
I think I read about bismuth crystals in another thread on here and I was surprised at how pretty th ...
28-10-2008 at 17:55
by: sonogashira
Using sodium hydrogen sulfate as a "dry acid"?
I had a thought about using sodium hydrogen sulfate (sodium bisulfate) to mix with NaCl, NaOAc etc. ...
25-10-2008 at 15:36
by: sonogashira
The short questions thread (1)
The [url=http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/129712]sigma-aldrich websi ...
22-10-2008 at 12:42
by: sonogashira
The short questions thread (1)
Thanks klute that looks like a really interesting paper. I can only see the first page but it looks ...
19-10-2008 at 16:21
by: sonogashira
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