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Manganese and it's salts - starting point & processes
I think you could reduce remaining MnO2 (from batteries), then the HCl could get you MnCl2. Don't th ...
1-1-2018 at 09:51
by: PirateDocBrown
Manganese and it's salts - starting point & processes
If you are using old batteries, likely a good deal of the MnO2 will have been reduced to Mn2O3.

...
1-1-2018 at 04:11
by: PirateDocBrown
Latest chemical order?
Got some zinc oxide! Whee!
30-12-2017 at 17:19
by: PirateDocBrown
Sodium Cyanate into Sodium Cyanide
I did it, too, with carbon. Small crucible, heat source was a Bernzomatic torch.


[Edited on 12/31 ...
30-12-2017 at 11:22
by: PirateDocBrown
Vacuum distillation - can it alone break azeotrope? Simple media bottle setup for alcohols & solvents
Methanol-water is not azeotropic.

But, no, vacuum distillation cannot break an ethanol-water azeo ...
25-12-2017 at 04:00
by: PirateDocBrown
My Senior Thesis: Removable Linkers for the Hexadehydro-Diels-Alder reaction
I did indeed! I got my undergrad there.
22-12-2017 at 12:10
by: PirateDocBrown
My Senior Thesis: Removable Linkers for the Hexadehydro-Diels-Alder reaction
You are at the U of M, Metacelcus? Ski-U-Mah! Who is your advisor there? I was there, 25 years ago.
...
21-12-2017 at 17:50
by: PirateDocBrown
Carbon tetrachloride
[rquote=501101&tid=78971&author=SWIM]

Funny how your perspective on risk changes with tim ...
20-12-2017 at 23:09
by: PirateDocBrown
Aniline Nitrate
Never add aniline to any sort of nitric acid. You are lucky you didn't blow yourself up.

Your dil ...
18-12-2017 at 06:33
by: PirateDocBrown
How to write chemical equations in organic chemistry
https://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/intro1.htm
17-12-2017 at 08:24
by: PirateDocBrown
In nanoscience what is the opposite of a capping agent??
That's a very good question. Why hasn't this been asked before?
16-12-2017 at 08:43
by: PirateDocBrown
Distilling HCl
So, yeah, lots of HCl outgassing, the boiling flask bubbles away merrily, yet little condenses. The ...
15-12-2017 at 23:56
by: PirateDocBrown
Distilling HCl
I'm giving this a go in real time, inspired by Nux Vomica's YouTube.

https://www.youtube.com/watc ...
15-12-2017 at 22:37
by: PirateDocBrown
Mystery Glassware Identification Thread
That kind of funnel/flask is an iodine flask. It's meant to be used to determine the degree of unsa ...
15-12-2017 at 16:36
by: PirateDocBrown
Latest chemical order?
[rquote=499660&tid=9890&author=woelen]Wow, LiCO3 :o
That's really special, you took it from ...
14-12-2017 at 02:52
by: PirateDocBrown
I had a conversation about cleaving alkenes.
I have considered periodate, but it would have the same drawbacks as MnO4-, i.e., oxidative attack o ...
12-12-2017 at 01:00
by: PirateDocBrown
I had a conversation about cleaving alkenes.
I didn't know there was so much on Erowid/Hive/Rhodium, however badly attributed. I thought it was m ...
11-12-2017 at 14:40
by: PirateDocBrown
I had a conversation about cleaving alkenes.
I was speaking to a fellow amateur chemist about the oxidative cleaving of alkenes, yielding ketones ...
11-12-2017 at 04:28
by: PirateDocBrown
latest glassware purchase
I have a well, as well as a screw top adapter, but also one of those that has a rubber fitment servi ...
9-12-2017 at 17:57
by: PirateDocBrown
Any good (read cheap) sources of Tartaric Acid UK?
I use the local brew and wine supply place for potassium bitartrate, tartaric acid, citric acid, pot ...
9-12-2017 at 17:54
by: PirateDocBrown
Latest chemical order?
8 oz LiCO3
4 oz V2O5
1 lb SnCl2
7-12-2017 at 01:16
by: PirateDocBrown
TetraChloroMethane Using Carbon and Chlorine ?
CCl4 used to be in every laundry room, as a spot remover.

It proved to be more toxic than was kn ...
6-12-2017 at 07:49
by: PirateDocBrown
TetraChloroMethane Using Carbon and Chlorine ?
Here it's compared to quartz.
5-12-2017 at 22:52
by: PirateDocBrown
TetraChloroMethane Using Carbon and Chlorine ?
[rquote=499515&tid=78554&author=unionised][rquote=498761&tid=78554&author=PirateDocB ...
5-12-2017 at 22:45
by: PirateDocBrown
TetraChloroMethane Using Carbon and Chlorine ?
[rquote=499509&tid=78554&author=unionised][rquote=498765&tid=78554&author=PirateDocB ...
5-12-2017 at 22:38
by: PirateDocBrown
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